Yokogawa Model SC25F pH SENCOM® sensor Instruction Manual

Instruction Manual Model SC25F pH SENCOM® sensor IM 12B6J1-41E-E 3rd edition 2 (BG) Всички улътвания за продукти от серията ATEX Ex ce лредлагат на английски език. Ако се нуждаете oт улътвания за продукти oт серията Ex на родния ви eзик, ce свържете c най-близкия oфис или представителство на фирма Yokogawa. (CZ) Všechny uživatelské příručky pro výrobky, na něž se vztahuje nevýbušné schváleni ATEX Ex, jsou dostupné v angličtině. Požadujete-li pokyny týkající se výrobků s nevýbušným schválením ve vašem lokálním jazyku, kontaktujte prosím vaši nejbližší reprezentačni kancelář Yokogawa. (D) Alle Betriebsanleitungen für ATEX Ex bezogene Produkte stehen in den Sprachen Englisch. Sollten Sie die Betriebs- anleitungen für Ex-Produkte in Ihrer Landessprache benötigen, setzen Sie sich bitte mit Ihrem örtlichem Yokogawa-Vertreter in Verbindung. (E) Todos los manuales de instrucciones para los productos antiexplosivos de ATEX están disponibles en inglés. Si desea solicitar las instrucciones de estos artículos antiexplosivos en su idioma local, deberá ponerse en contacto con la oficina o el representante de Yokogawa más cercano. (F) Tous les manuels d’instruction des produits ATEX Ex sont disponibles en langue anglaise. Si vous nécessitez des instructions relatives aux produits Ex dans votre langue, veuillez bien contacter votre représentant Yokogawa le plus proche. (GB) All instruction manuals for ATEX Ex related products are available in English. Should you require Ex related instructions in your local language, you are to contact your nearest Yokogawa office or representative. (DK) Alle brugervejledninger for produkter relateret til CE er tilgængelige på engelsk. Skulle De ønske yderligere oplysninger om håndtering af CE produkter på eget sprog, kan De rette henvendelse herom til den nærmeste Yokogawa afdeling eller forhandler. (GR) Ολα τα εγχειριδια λειτουργιας των προιοντων με ATEX Ex διατιθενται στα Αγγλικα. Σε περιπτωση πον χρειαζεοτε οδηγιεξ σχετικα με Ex στην τοπικη γλωσσα παρακαλονμε επικοινωνηστε με το πλησιεστερο γραφειο τηζ Yokogawa η αντιπροσωπο τηξ. (EST) Kõik ATEX Ex toodete kasutamisjuhendid on esitatud inglise keeles. Ex seadmete muukeelse dokumentatsiooni saamiseks pöörduge lähima lokagava (Yokogawa) kontori või esindaja poole. (H) Az ATEX Ex mûszerek gépkönyveit angol nyelven adjuk ki. Amennyiben helyi nyelven kérik az Ex eszközök leírásait, kérjük keressék fel a legközelebbi Yokogawa irodát, vagy képviseletet. (I) Tutti i manuali operativi di prodotti ATEX contrassegnati con Ex sono disponibili in inglese. Se si desidera ricevere i manuali operativi di prodotti Ex in lingua locale, mettersi in contatto con l’ufficio Yokogawa più vicino o con un rappresentante. IM 12B6J1-41E-E (LV) Visas ATEX Ex kategorijas izstrâdâjumu Lietoðanas instrukcijas tiek piegâdâtas angïu valodâs. Ja vçlaties saòemt Ex ierîèu dokumentâciju citâ valodâ, Jums ir jâsazinâs ar firmas Jokogava (Yokogawa) tuvâko ofisu vai pârstâvi. (LT) Visos gaminiø ATEX Ex kategorijos Eksploatavimo instrukcijos teikiami anglø kalbomis. Norëdami gauti priestaisø Ex dokumentacijà kitomis kalbomis susisiekite su artimiausiu bendrovës Yokogawa biuru arba atstovu. 3 (PL) Wszystkie instrukcje obsługi dla urządzeń w wykonaniu przeciwwybuchowym Ex, zgodnych z wymaganiami ATEX, dostępne są w języku angielskim. Jeżeli wymagana jest instrukcja obsługi w Państwa lokalnym ję zyku, prosimy o kontakt z najbliższym biurem Yokogawy. (RO) Toate manualele de instructiuni pentru produsele ATEX Ex sunt in limba engleza. In cazul in care doriti instructiunile in limba locala, trebuie sa contactati cel mai apropiat birou sau reprezentant Yokogawa. (M) Il-manwali kollha ta’ l-istruzzjonijiet għal prodotti marbuta ma’ ATEX Ex huma disponibbli bl-Ingliż. Jekk tkun teħtieģ struzzjonijiet marbuta ma’ Ex fil-lingwa lokali tiegħek, għandek tikkuntattja lill-eqreb rappreżentan jew uffiććju ta’ Yokogawa. (S) Alla instruktionsböcker för ATEX Ex (explosionssäkra) produkter är tillgängliga på engelska. Om Ni behöver instruktioner för dessa explosionssäkra produkter på annat språk, skall Ni kontakta närmaste Yokogawakontor eller representant. (NL) Alle handleidingen voor producten die te maken hebben met ATEX explosiebeveiliging (Ex) zijn verkrijgbaar in het Engels. Neem, indien u aanwijzingen op het gebied van explosiebeveiliging nodig hebt in uw eigen taal, contact op met de dichtstbijzijnde vestiging van Yokogawa of met een vertegenwoordiger. (SF) Kaikkien ATEX Ex-tyyppisten tuotteiden käyttöhjeet ovat saatavilla englannin-. Mikäli tarvitsette Ex-tyyppisten tuotteiden ohjeita omalla paikallisella kielellännne, ottakaa yhteyttä lähimpään Yokogawa-toimistoon tai -edustajaan. (P) Todos os manuals de instruções referentes aos produtos Ex da ATEX estão disponíveis em Inglês. Se necessitar de instruções na sua língua relacionadas com produtos Ex, deverá entrar em contacto com a delegação mais próxima ou com um representante da Yokogawa. (SK) Všetky návody na obsluhu pre prístroje s ATEX Ex sú k dispozícii v jazyku anglickom. V prípade potreby návodu pre Ex-prístroje vo Vašom národnom jazyku, skontaktujte prosím miestnu kanceláriu firmy Yokogawa. (SLO) Vsi predpisi in navodila za AEX Ex sorodni pridelki so pri roki v anglišèini. Èe so Ex sorodna navodila potrebna v vašem tukejnjem jeziku, kontaktirajte vaš najbliši Yokogawa office ili predstaunika. IM 12B6J1-41E-E 4 IM 12B6J1-41E-E 5 Contents 1. PREFACE 6 Introduction Unpacking and Checking Warranty and Service Serial Number definition 6 6 6 7 2. GENERAL SPECIFICATIONS 8 1.1 1.2 1.3 1.4 2.1 Measuring elements 2.2 Wetted parts 2.3 Functional specifications (at 25°C) 2.4 Dynamic specifications 2.5 Operating range 2.6 Transmission signal (Data + and Data -) 2.7 Power supply (Supply+ versus Supply Gnd) 2.8 Regulatory standards 2.9 Shipping details 2.10 Environment and operational conditions 8 8 8 8 8 9 9 9 12 12 3 INSTALLATION OF SC25F 13 13 13 13 3.1 Typical installation 3.2 Preparing the sensor for use 3.3 Mounting the sensor 4 DIMENSIONS 16 5. WIRING 17 6. GENERAL CALIBRATION & MAINTENANCE PROCEDURE 17 6.1 Calibration for pH measurement 6.2 Maintenance of the SC25F sensor 17 18 7. MODEL CODE 19 8. SPARE PARTS 19 9. EU DECLARATION OF CONFORMITY 20 10. CHEMICAL COMPATIBILITY CHART 22 IM 12B6J1-41E-E 6 1. PREFACE 1.1 Introduction This instruction manual provides information for the installation and use of the SC25F SENCOM® sensor. This digital sensor shows how Yokogawa applies the motto “Simply the Best” to sensor technology. Setup of the sensor is very easy because all sensor specific characteristics, such as calibration data, are stored in the sensor. The SC25F SENCOM® sensor holds four separate measuring elements: • pH glass electrode. • Long life saturated Ag/AgCl reference system. • Integral Pt1000 element for accurate temperature measurements. • Solid Titanium LE electrode for accurate pH measurements. Other valuable features of the sensor: • PTFE reference diaphragm to prevent fouling. • Polymerized electrolyte to extend the sensor lifetime. • Available in different versions, a G-glass version for general purpose applications, and a L-glass version for harsh applications and high process temperatures. Both the G-glass as the L-glass version are available in two different lengths, 120 mm and 225 mm. •Versatile in-line, immersion or off-line installation. Optional quick-removal adapters in both stainless steel and titanium are available to make calibration and maintenance even easier. The SC25F is provided with a multipole M9 male connector for connection to the Yokogawa FLXA analyzer using the WU11 interconnection (and extension) cable for SENCOM® sensors. This cable, available in several lengths, is specified for reliable transfer of digital signals and especially designed to be installed in a heavy industrial environment. The double shielded cable will protect both the sensor and the analyzer for IM 12B6J1-41E-E interference from high voltages and currents which are present on other cables. 1.2 Unpacking and Checking Upon delivery, unpack the sensor carefully and inspect it to ensure that it is not damaged during shipment. If damage is found, retain the original packing material and immediately notify the carrier and the relevant local Yokogawa Sales Office. Make sure the Model Code and Serial Number on the sensor are the same as on the packing list. Also check if option(s) that were ordered, are included and correct. 1.3 Warranty and Service Yokogawa products are guaranteed free from defects in workmanship and materials under normal use and service for a period of (typically) 12 months from the date of shipment from the manufacturer. Individual Sales organizations can deviate from the typical warranty period, and the conditions of sale relating to the original purchase order should be consulted. Damage caused by wear and tear, inadequate maintenance, corrosion, or by the effects of chemical processes is excluded from this warranty coverage. In the event of a warranty claim, the defective goods should be sent (freight paid) to the Service Department of the relevant Yokogawa Sales office for repair or replacement (at Yokogawa’s discretion). The following information must be included in the letter accompanying the returned goods: • Model Code and Serial Number. • Original Purchase Order and Date. • Length of time in service and description of the process. • Description of the fault and circumstances of the failure. • Process/environmental conditions that may be related to the failure of the sensor. • Statement as to whether warranty or nonwarranty service is requested. • Complete shipping and billing instructions for return of material, plus the name and 7 phone number of a contact person that can be reached for further information. • Clean Statement Returned goods that have been in contact with process fluids must be decontaminated and disinfected prior to shipment. Goods should carry a certificate to this effect, for the health and safety of our employees. Material Safety Data sheets must be included for all components of the process to which the sensor(options) have been exposed. 1.4 Serial Number definition The Serial Number is defined by nine (9) alphanumeric characters: X1X2 Production Location X3X4 Year/Month code X5X6X7X8X9 Tracking number Example: N3P600028 Method used for year/month numbering Table 1: Production Year code Table 2: Production Month code Year 2014 2015 2016 2017 2018 2019 2020 2021 2022 2023 2024 2025 Month January February March April May June July August September October November December Year code Year P 2026 R 2027 S 2028 T 2029 U 2030 V 2031 W 2032 X 2033 Y 2034 Z 2035 1 2036 2 2037 Year code 3 4 5 6 7 8 9 A B C D E Month code 1 2 3 4 5 6 7 8 9 A B C IM 12B6J1-41E-E 8 2. GENERAL SPECIFICATIONS 2.1 Measuring elements 2.2 Wetted parts Sensor body Measuring sensor Reference junction Earth pin O-ring : : : : pH glass electrode Silver Chloride reference Solid Titanium electrode Pt1000 temperature sensor : : : : : Glass, PEEK G-glass or L-glass Porous PTFE Solid Titanium FKM (Viton) and EPDM 2.3 Functional specifications (at 25°C) Measuring system Isothermal point : pH 7 Reference system : Ag/AgCl with saturated KCl Glass impedance - G-glass : 400 MΩ nominal - L-glass : 775 MΩ nominal Liquid outlet : Non-flow junction Junction resistance : < 10 kΩ Temperature element : Pt1000 to IEC 751 Asymmetry potential(zero) : 8 ± 15 mV Slope : > 96 % (of theoretical value) Note: T  he SC25F temperature sensor is designed for cell compensation and for indication. It is NOT designed for process temperature control. 2.4 Dynamic specifications Startup time sensor : < 60 sec. Response time pH : t90 < 15 sec. (for 7 to 4 pH step at 25 ºC) Response time temperature : t90 < 1.5 min. (for 10 °C step) Stabilization time pH : < 2 min. (for 0.02 pH unit during 10 sec.) 2.5 Operating range pH* Temperature** - G-glass - L-glass Pressure (static) *** : 0 to 14 : -10 °C to 80 °C (14 °F to 176 °F) : +15 °C to 125 °C (59 °F to 257 °F) : p(bar) 10 5 0 -10 Conductivity 0 25 50 100 130 Temp. (ºC) : > 10 µS/cm Note* : T  he pH operating range is 0-14 pH, but using the sensor at temperature- and / or pH-extremes will seriously shorten the lifetime. Note** : The operating temperature for sensor in combination with PR10 retractable fitting is limited to 80 ºC Note*** : Process pressure fluctuations will shorten the lifetime of the sensor IM 12B6J1-41E-E 2.6 Transmission signal (Data + and Data -) General : Bi-directional digital communication (RS 485) with limited MODBUS support Data rate : 9600 b/s (8,E,1) Output function : pH or temperature compensated pH Temperature Junction resistance Sensor details (Model, Serial Number, production date) Sensor calibration data (zero, slope, temperature offset) Sensor status signals (e.g. Glass impedance detection) Note: T  he output functions and settings of the sensor are accessible using a dedicated device such as the Yokogawa FLXA analyzer. 2.7 Power supply (Supply+ versus Supply Gnd) Operating range : +2.7 to +3.6 VDC Power consumption : ≤ 20 mW Pin # 1 2 3 4 5 Signal description Data Data + Supply + Shield Supply Gnd 9 2 1 3 5 4 Fig 1: S  ensor connector (front view) with gold plated contacts 2.8 Regulatory standards CE : Decision 768/2008/EC - ATEX : Directive 94/9/EC, as amended by Regulation (EC) no. 1882/2003 - Certificate no. : DEKRA 11ATEX0064 X for II 1 G Ex ia IIC T3...T6 Ga - Electrical data : For sensor input circuits (by connector) connected to a certified intrinsically safe circuit with the following maximum values : Ui = 6.1 V; Ii = 230 mA; Pi = 1.2 W; Li = 4 µH; Ci = 30 µF ::or Certified intrinsically safe Yokogawa transmitter Model FLXA21. - Special conditions (X) : T6 for Tamb. -40 °C to +60 °C T5 for Tamb. -40 °C to +75 °C T4 for Tamb. -40 °C to +110 °C T3 for Tamb. -40 °C to +125 °C Electrostatic charges on the sensor enclosure shall be avoided. - Pressure : Directive 97/23/EC, as amended by Regulation (EC) no. 1882/2003 - Applying article : 3.3 (Sound Engineering Practice) Damaging the screw thread of the sensor might influence the maximum process pressure. - EMC : Directive 2004/108/EC IEC 61326-1: 2005 Class A (control and laboratory use) IEC 61326-1: 2005 (use in industrial locations) - Low Voltage : Directive 2006/95/EC Sensor contains glass parts which if broken can cause cutting injuries. - WEEE - RoHS IECEx Applying standards Certificate no. : Directive 2012/19/EU : Directive 2011/65/EU : IEC 60079-0: 2007; IEC 60079-11: 2006; IEC 60079-26: 2006 : IECEx DEK 11.0065X for Ex ia IIC T3...T6 Ga IM 12B6J1-41E-E 10 CSA Certificate no. Master contract no. : 2516979 : 182892 IS, Class I Div. 1, GP A, B, C, D T3…T6 Electrical data : For sensor input circuits (by connector), connected to a certified intrinsically safe circuit, with the following maximum values: Ui = 6.1 V; Ii = 230 mA; Pi = 1.2 W; Li = 4 μH; Ci = 30 μF or Certified intrinsically safe Yokogawa transmitter Model FLXA21 series. Ambient temperature : T6 for Tamb. -40 °C to +60 °C T5 for Tamb. -40 °C to +75 °C T4 for Tamb. -40 °C to +110 °C T3 for Tamb. -40 °C to +125 °C Note: Intrinsically safe when connected as per Control Drawing FF1-K1224QV (see Fig 2) Control Drawing CSA Transmitter + - G The SC25F SENCOM® sensor shall be installed to a certified intrinsically safe circuit meeting the entity parameters of the sensor as shown in the table as maximum values, or to a certified intrinsically safe Yokogawa transmitter Model FLXA21 series. 81 82 83 84 85 86 87 When installing this equipment, follow the manufacturer’s control drawing. Installation should be in accordance with Canadian Electrical Code, Part 1 or CEC, Part 1. WU11 cable terminals 82-84, 86-87. Maximum cable length: 100 m. Cable diameter: 5.8mm To prevent ignition of flammable or or combustible atmospheres, disconnect power before servicing or read, understand and adhere to the manufacturer’s live maintenance procedures. Hazardous location Maximum values Sensor 6.1 V Ui 230 mA Ii 1.2 W Pi 4 µH Li 30 µF Ci IS, Class I Div.1, GP A, B, C, D T3/T4/T5/T6 Ta 125 ºC/110 ºC/75 ºC/60 ºC SC25F - - 120 225 AGP25 ALP25 120mm 225 mm General purpose High temp. chemical resistant Fig 2: FF1-K1224QV Control drawing CSA  IM 12B6J1-41E-E 11 FM Certificate no. :3  046277 IS, CL I Div. 1, GP A, B, C, D T3…T6 Electrical data : For sensor input circuits (by connector), connected to a FM approved intrinsically safe apparatus meeting the entity parameters of the SENCOM® sensor: Ui = 6.1 V; Ii = 230 mA; Pi = 1.2 W; Li = 4 μH; Ci = 30 μF or FM approved intrinsically safe Yokogawa transmitter Model FLXA21 series. Ambient temperature: T6 for Tamb. -40 °C to +60 °C T5 for Tamb. -40 °C to +75 °C T4 for Tamb. -40 °C to +85 °C T3 for Tamb. -40 °C to +85 °C Note: Intrinsically safe when connected as per Control Drawing FF1-K1224QT (see Fig 3) Control Drawing FM The SC25F SENCOM® sensor shall be installed to a FM approved intrinsically safe apparatus meeting the entity parameters of the sensor as shown in the table as maximum values, or to a FM certified intrinsically safe Yokogawa transmitter Model FLXA21 series. Transmitter + - G 81 82 83 84 85 86 87 WU11 cable terminals 82-84, 86-87. When installing this equipment, follow the manufacturer’s control drawing. Installation should be in accordance with ANSI/ISA RP 12.06.01 “Installation of Intrinsically Safe Systems for Hazardous (Classified) Locations” and the National Electrical Code (ANSI/NFPA 70). Maximum cable length: 100 m. Cable diameter: 5.8mm Classified location To prevent ignition of flammable or or combustible atmospheres, disconnect power before servicing or read, understand and adhere to the manufacturer’s live maintenance procedures. Input parameter Sensor 6.1 V Ui 230 mA Ii 1.2 W Pi 4 µH Li 30 µF Ci IS, CL I Div.1, GP A, B, C, D T3/T4/T5/T6 Ta 85 ºC/85 ºC/75 ºC/60 ºC SC25F - - 120 225 AGP25 ALP25 120mm 225 mm General purpose High temp. chemical resistant Fig 3: FF1-K1224QT Control drawing FM  IM 12B6J1-41E-E 12 Note: When the sensor has been connected to not intrinsically safe equipment which exceeds the restrictions regarding the sensor input circuit (see electrical data), the sensor is not suitable anymore for intrinsically safe use. 2.9 Shipping details Package size (L x W x H) : 1  20mm version: 300 x 100 x 75 mm (11.8 x 3.9 x 3.0 inch) 225 mm version: 435 x 60 x 60 mm (17.1 x 2.4 x 2.4 inch) Package weight : app. 0.25 kg (0.55 lbs) 2.10 Environment and Storage temperature Sensor connection Water proof IM 12B6J1-41E-E operational conditions : -10 ºC to 50 °C (14 ºF to 122 °F) : Hot swapping possible : IP67 (conform IEC 60529) 3 INSTALLATION OF SC25F For optimum measurement results, the SC25F should be installed in a location that offers an acceptable representation of the process composition and DOES NOT exceed the specifications of the sensor. The SC25F is designed with PG13.5 threaded connection to allow installation in a wide variety of applications. 3.1 Typical installation The SC25F sensor is designed for versatile in-line, immersion or off-line installation. For best results the SC25F should be mounted with the process flow coming towards the sensor, and positioned at least 15° above the horizontal plane to eliminate air bubbles in the pH glass bulb (see Figure 4). GOOD 3.3 Mounting the sensor The simplest mounting is to use the PG13.5 threaded connection of the sensor. The sensor is standard with a slide ring (Ryton) and an O-ring (Silicon) for direct mounting in a fitting provided with PG13.5 thread (see Figure 5). Other O-ring materials are available as a spare part (see Section 8 of this Instruction Manual). Note: W  hen sensor is installed in a fitting which is already provided with a spacer for the sensor, remove the pre-installed slide ring and O-ring and follow the installation instructions of the fitting. GOOD Slide ring (Ryton) Slide ring (Ryton) O-ring Slide ring (Ryton) O-ring HORIZONTAL O-ring 15º 15º Adapter M25 x 1,5 - PG13.5 K1520JN (PVC) K1520JP (SS) K1500DV (PVDF) INCORRECT When mounting in FD20 FF20 FS20 use O-ring 11 x 3 Fig 4: Mounting positions of sensor 44 3.2 Preparing the sensor for use Remove the sensor from its shipping box and slide off the so-called ‘wet pocket’, thePG13.5 PG13.5 tube filled with solution to prevent drying out of the measuring elements during shipment Sensor or storage. During shipment, electrolyte M25 in x 1.5 Holder Fitting PG13.5 Plastic FS40 the sensor could be dislocated. To correct Plastic FF40 3/4”NPT this, place the sensor upright for 24 hours. Before installing the sensor in the process it Adapter PG13.5 should be calibrated. A general calibration M25 x 1,5 Adapter K1500DV (PVDF) PG13.5 to 3/4”NPT procedure is described in Section 6 of this K1520JM (PVC) K1523JB (PPO) K1520JP (SS) Instruction Manual. K1523JD (SS) Fig 5: Simple mounting of sensor in PR10 retractable fitting 60 ng 13 IM 12B6J1-41E-E 14 Slide ring (Ryton) O-ring Examples of mounting the SC25F sensor using an adapter are given in Figures 6, 7, 8 and 9. PG13.5 Adapter PG13.5 to SC-fitting K1523JA (PPO) K1523JC (SS) FF40-S22 FS40-S22 Adapter PG13.5 to SC-fitting K1523JA (PPO) K1523JC (SS) Fitting Plastic FS40 Plastic FF40 3/4”NPT Adapter PG13.5 to 3/4” K1523JB (PPO K1523JD (SS) Slide ring (Ryton) O-ring Slide ring (Ryton) O-ring Adapter M25 x 1,5 - PG13.5 K1520JN (PVC) K1520JP (SS) K1500DV (PVDF) PG13.5 When mounting in FD20 FF20 FS20 use O-ring 11 x 3 10 ø 10.7 -0.7 The SC25F sensor can also be mountedSlide in ring (Ryton) O-ring other fittings using a quick-removal adapter. These adapters are available as a spare part and ordering information of these parts is given in Section 8 of this Instruction Manual. For a detailed description of these adapters see Section 4. ø 13.5 O-ring 29.74 x 3.53 PG13.5 PG13.5 Fig 6: M  ounting of sensor in FD20/ FF20/FS20 fitting using M25x1.5 adapter M25 x 1.5 K1500DV/ K1520JN / K1520JP 44 ø 12 223 ±2.0 / 328 ±2.0 ng (Ryton) O-ring 60 PG13.5 Note: F  irst install the sensor in the adapter before it is mounted in the fitting. 120 / 225 ±2.0 Wrench 19 Note:  ounting the sensor in fittings where M <21 the sealing is situated nearby the sensortip, uncorrect placement of the sensor will damage the measuring glass elements. Please handle with care. <25 nnector 3/4”NPT IM 12B6J1-41E-E Adapter PG13.5 to 3/4”NPT Adapter PG13.5 M25 x 1,5 K1500DV (PVDF) Fig 7: M  ounting of sensor in plastic FS40 / FF40 fitting, using adapter Sensor K1523JA Holder / K1523JC PG13.5 Adapter PG13.5 to SC-fi K1523JA (PPO) K1523JC (SS) 15 <21 or 223 ±2.0 / 328 ±2.0 M9-Connector ch 19 G13.5 ø 12 Slide ring (Ryton) O-ring Slide ring (Ryton) O-ring Slide ring (Ryton) O-ring Adapter PG13.5 to 3/4”NPT K1523JB (PPO) K1523JD (SS) Seal, e.g. with Teflon tape ø 12 3/4”NPT <25 ø 10.7 -0.7 1/4”NPT PG13.5 FF40-S22 FS40-S22 Adapter PG13.5 to SC-fitting K1523JA (PPO) K1523JC (SS) Fitting Plastic FS40 Plastic FF40 Flow fitting SS K1598AC 60 Adapter PG13.5 to SC-fitting K1523JA (PPO) K1523JC (SS) 3/4”NPT Adapter PG13.5 to 3/4”NPT K1523JB (PPO) K1523JD (SS) 1/4”NPT PG13.5 10 7 -0.7 PG13.5 Slide ring (Ryton) O-ring 120 / 225 ±2.0 yton) O-ring Wrench 19 ø 13.5 O-ring 29.74 x 3.53 Fig 8: M  ounting of sensor in metal FF40 fitting, using adapter K1523JA / K1523JC Adapter PG13.5 to SC-fitting K1523JA (PPO) K1523JC (SS) Fig 9: M  ounting of sensor in fitting K1598AC, using adapter K1523JB / K1523JD IM 12B6J1-41E-E 4 DIMENSIONS Dimensions in mm M25 x 1.5 <21 M9-Connector Fig 11: D  imensions adapters K1500DV, K1520JN, K1520JP Wrench 19 PG13.5 Slide ring (Ryton) O-ring 120 / 225 ±2.0 h Slide ring (Ryton) O-ring Fig 12: D  imensions adapters K1523JA, K1523JC PG 13,5 60 ø 10.7 -0.7 Ø13.5 <25 ø 12 10 PG13.5 /4”NPT PO) S) SS 44 PG 13,5 223 ±2.0 / 328 ±2.0 yton) 16 3/4"NPT Fig 10: Dimensions SC25F Sensor IM 12B6J1-414E-E Adapter PG13.5 to SC-fitting K1523JA Fig 13: (PPO) Dimensions adapters K1523JC (SS) K1523JB, K1523JD FF40-S22 FS40-S22 Adapte PG13.5 K1523J K1523J 17 5. WIRING The SC25F is provided with a multipole M9 male connector for connection to the Yokogawa FLXA analyzer using the WU11 interconnection cable for SENCOM® sensors. The connections of this M9 male connector (see Section 2.7 for details), the WU11 interconnection cable and the FLXA terminal strip are given in Table 3. Table 3: Definition M9 sensor connector pin to WU11 cable and FLXA analyzer M9 Pin # 1 2 3 4 5 WU11 wire # 83 84 87 82 86 WU11 wire color FLXA terminal # Signal description Yellow 83 Data Green 84 Data + Brown 87 Supply + Black 82 Shield White 86 Supply Gnd 6. GENERAL CALIBRATION & MAINTENANCE PROCEDURE Calibration of the SC25F pH SENCOM® sensor can be done on site with the FLXA analyzer connected, or in the laboratory with another FLXA analyzer or with the dedicated Yokogawa SENCOM® PC software, model SPS24. When using another FLXA analyzer, it has to be set correctly for each calibration. Refer to the FLXA analyzer Instruction Manual for details. After calibration all data will be stored in the sensor itself. If the sensor is reconnected to the FLXA analyzer in the field, the calibration data of the sensor is automatically read by the analyzer. 6.1 Calibration for pH measurement To calibrate the SC25F pH SENCOM® sensor, two buffer solutions with known pH values are required. It is recommended that one buffer solution has a value near to pH 7.00. Depending on the process value to be measured, the second buffer solution should be either acidic (below pH 7.00) or alkaline (above pH 7.00). Normally the IEC buffers (pH 4.01, 6.87 and 9.18) are used. The following is a very general 2-point calibration procedure: 1. Clean the sensor using a 5% solution of HCl; 2. Rinse sensor thoroughly with demineralized water; 3. Immerse the sensor in the first buffer (pH 6.87 is recommended) and execute calibration as described in the instruction manual of the analyzer or SPS24 PC software; 4. Rinse sensor thoroughly with demineralized water; 5. Immerse the sensor in the second buffer (pH 4.01 or 9.18 is recommended) and execute calibration as described in the instruction manual of the analyzer or SPS24 PC software; 6. Rinse sensor thoroughly with demineralized water. During calibration, the temperature compensation should be active. The FLXA analyzer automatically compensates for the sensitivity change of the pH sensor at different temperatures. After calibration, replace or re-install the sensor into the process. IM 12B6J1-41E-E 18 6.2 Maintenance of the SC25F sensor A pH sensor requires routine maintenance to keep the measuring elements clean and functioning. Depending on the process, different cleaning solutions may be required.  void cleaning the complete sensor with solution. Some cleaning solutions will A damage the modelcode sticker and connector which are placed on the electronic housing on top of the sensor. Only clean the measuring elements at the bottom side of the sensor. In most cases cleaning with water, iso-propanol or methanol is sufficient. In other cases the measuring elements of the sensor have to be cleaned with specific solutions. Examples: 1. Deposits of limes, hydroxides or carbonates can be removed by immersing the bottom part of the sensor in a solution containing dilute hydrochloric acid (5% is recommended). Afterwards rinse the sensor with water. 2. Deposits of oil and fat can be removed with hot water with a detergent. When the results are unsatisfactory, a mild (carbonate based) abrasive can be used. 3. Protein deposits should be removed with a protein enzymatic solution, for instance a solution containing 8.5 mL concentrated hydrochloric acid and 10 grams of pepsin in 1 liter of water. Note: A  void cleaning with non-polar solvent like tri-chloro ethylene, toluene or hexane. The non-polar solvents will break up the gel-layer on the pH glass bulb and requires that the sensor has to be soaked in water for at least 12 hours before it will function again. The Teflon diaphragm of the sensor can be regenerated by putting it in hot (± 70°C, 158°F) 3 molar Potassium Chloride (KCl) solution and letting it cool down to room temperature. This procedure clears the diaphragm and will soak the diaphragm with conductive KCl again. IM 12B6J1-41E-E 19 7. MODEL CODE Model Code Suffix Code Option SC25F sensor type - AGP25 - ALP25 sensor length -120 -225 Description SENCOM® pH Sensor: pH, REF, LE, Temp. General purpose model High temp. chemical resistant model 120mm 225mm 8. SPARE PARTS K1500BV K1500BZ K1500GR K1524AA O-rings O-ring set (6 pcs.), 11x3 mm, EPDM O-ring set (6 pcs.), 11x3 mm, Viton O-ring set (8 pcs.), 11x3 mm, Silicon O-ring 11x3 mm (Silicon) and Slide ring (Ryton) Connection equipment BA10 Junction box for SENCOM® Sensor WU11-M9-xx-WP-V Interconnection Cable for SENCOM® Sensor, available lengths xx (03, 05, 10, 20 meter) WU11-M9-30-CN-V Extension Cable for SENCOM® Sensor, length 30 meter K1520BA K1520BB K1520BC K1520BD K1520BE Buffer solutions Buffer solutions pH 4.01, pH 6.87, pH 9.18 (500 ml each) Buffer solution pH 1.68 (500 ml) Buffer solution pH 4.01 (500 ml)) Buffer solution pH 6.87 (500 ml) Buffer solution pH 9.18 (500 ml) K1500DV K1520JN K1520JP K1523JA K1523JB K1523JC K1523JD Adapters Adapter, PG13.5 Adapter, PG13.5 Adapter, PG13.5 Adapter, PG13.5 Adapter, PG13.5 Adapter, PG13.5 Adapter, PG13.5 K1598AC1) Fittings Flow fitting (incl. 3.1 certificate), Stainless Steel to to to to to to to M25x1.5, PVDF M25x1.5, PVC M25x1.5, Stainless Steel FF40/FS40 fitting, PPO (Noryl) ¾”NPT, PPO (Noryl) FF40/FS40 fitting, Stainless Steel ¾”NPT, Stainless Steel 1) Note : Adapter K1523JB or K1523JD needed to fit the sensor. IM 12B6J1-41E-E 20 9. EU DECLARATION OF CONFORMITY YOKOGAWA EU DECLARATION OF CONFORMITY Yokogawa Process Analyzers Europe B.V. Euroweg 2 3825 HD Amersfoort The Netherlands We: herewith declare under our sole responsibility that the product, model: SC25F further specified with model suffix- and option codes: As listed in Annex-1 in this document is manufactured in accordance with the requirements for CE-marking of products as stated in EC Decision: 768/2008/EC on a common framework for the marketing of products by applying the following standards: EN-ISO 9001: 2008 Quality management systems - Requirements Subject product is: In compliance with the essential requirements of the specific product legislation: - EMC Directive 2004/108/EC by applying the following standards: IEC 61326-1: 2006 Class A Electrical equipment for measurement, control and laboratory use – EMC requirements – Part 1: General requirements. IEC 61326-2-3: 2006 Electrical equipment for measurement, control and laboratory use – EMC requirements – Part 2-3: Particular requirements – Test configurations, operational conditions and performance criteria for transducers with integrated or remote signal conditioning. • - LVD Directive 2006/95/EC by applying the following standards: IEC 61010-1: 2010 Safety requirements for electrical equipment for measurement, control and laboratory use – Part 1: General requirements. - Pressure Equipment Directive 97/23/EC (PED) As amended by Regulation (EC) no. 1882/2003, by applying: Article 3.3: Sound Engineering Practice - RoHS by applying: Category 9: Directive 2011/65/EU Industrial monitoring and control instruments, ion selective electrode - Explosive atmospheres Directive 94/9/EC (ATEX) As amended by Regulation (EC) no. 1882/2003, by applying the following standards: EN 60079-0: 2009 Explosive atmospheres – Part 0: Equipment – General requirements EN 60079-11: 2007 Explosive atmospheres – Part 11: Equipment protection by intrinsic safety “i” EN 60079-26: 2007 Explosive atmospheres – Part 26: Equipment with equipment protection level (EPL) Ga The provisions fulfilled are: • • II 1 G Ex ia IIC T3...T6 Ga Number of the EC-type Examination Certificate: DEKRA 11 ATEX 0064 X Name of the notified body: DEKRA Certification B.V. Identification number of the notified body: 0344 Address of the notified body: Meander 1051, 6825 MJ Arnhem, The Netherlands Produced according to appropriate quality control procedures. The CE-mark has been affixed on the product in 2013 for the first time. If applicable, the product is checked against the latest official released revision of the standards mentioned above; differences do not affect the certified product identified on this declaration. Amersfoort, 01 July 2014 H. Leijten General Manager Yokogawa Process Analyzers Europe B.V. 1/2 IM 12B6J1-41E-E 21 Annex-1 Model Code Suffix Code Option SC25F sensor type - AGP25 - ALP25 sensor length -120 -225 Description SENCOM® pH Sensor: pH, REF, LE, Temp. General purpose model High temp. chemical resistant model 120mm 225mm IM 12B6J1-41E-E 22 10. CHEMICAL COMPATIBILITY CHART Chemical Compatibility Chart Material Inorganic acid Hydrochloric acid Nitric acid - - O O O O O O O O O - - - O O O O O O O O O O Organic acid Alkali Acid salt Basic salt Neutral salt Oxidizing agent 20 95 O O O X - - - - - O O O - - - O O fuming O O O - - - - - - O O O - - - O O O 10 O O O O O O - - - O O O O O X O O O sat. O O O X X X - - - O O O O O X O O O 25 O O X O X - O O O O O O O O O O O O 50 - - - - - - O O O O O O X X X O O O 95 - - - - - - O O O O O O - - - O O O O O O - - - O O O X X - O O O O O O O O O - - - - - - 25 O O O O O O 50 O O O O O O X - - O O O O O O O O O 95 X X - O O O X - - O O O O O O O O O 40 O O O - - - - - - O O O - - - X X X 75 O O X - - - - - - O O O - - - - - - 10 - - - O O O O O O O O O O O O O O O glacial - - - X X X O O O O O O O O X O O O 80 - - - O O X X X - O O O X X X O O O Citric acid 50 O O O O O O X X X O O O O O O O O O Calcium hydroxide sat. O O O O O O O O O O O O O O O O O O Potassium hydroxide 50 O O O O X - O X - O O O O O O O O X Sodium hydroxide 40 X X X O X - X X - O O O O O O O O X Hydrofluoric acid Organic solvent 100 - - 60 100 O X 20 60 O O fuming Phosphoric acid O = can be used; X = shortens useful life; - = cannot be used; Blank = no data available 100 20 O O 60 100 O O 20 60 O O 60 20 O 50 20 100 10 Conc.% Sulfiric acid Glass PEEK 60 Temp. °C PTFE (teflon) Ti 100 EPDM Viton Acetic acid Formic acid Ammonia in water 30 X X X O O O X X - O O O O O O O O X Ammonium chloride sat. O O O O O O O O O O O O O O O O O O Zinc chloride 50 O O O O O O O O O Iron(III) chloride 50 O O O O Sodium sulfite sat. - - - O O O O O O O O O O O O O O O Sodium carbonate sat. O O O O O O O O O O O O O O O O O O Potassium chloride sat. O O O O O O O O X O O O O O O O O O Sodium sulfate sat. O O O O O O O O O O O O O O O O O O Calcium chloride sat. O O O O O O O O O O O O O O O O O O Sodium chloride sat. O O O O O O O O O O O O O O O O O O Sodium nitrate 50 O O O O O O O O O O O O O O O O O O Aluminium chloride sat. O O O O O O O O X O O O O O O O O O Hydrogen peroxide 30 O O O O O X O O O O O O O O O O O O Sodium Hypochloride 50 O O X O O O X - - O O O O O O O O O Potassium dichromate sat. O O O O O O O O O Chlorinated lime Ethanol Cyclohexane 80 O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O X X X O O O X - - O O O O O O O O O O O O O O O O O O - - - O O O O O O O O O O O O Toluene - - - - - - O O O O O O O O O O O O Trichloroethane X X X - - - O O O O O O O O O O O O Water O O O O O O O O O O O X O O O O O O Note: Information in this list is based on our general experience and literature data and given in good faith. However Yokogawa is unable to accept responsibility for claims related to this information. IM 12B6J1-41E-E 23 IM 12B6J1-41E-E YOKOGAWA ELECTRIC CORPORATION World Headquarters 9-32, Nakacho 2-chome, Musashino-shi Tokyo 180-8750 Japan www.yokogawa.com YOKOGAWA ELECTRIC ASIA Pte. LTD. 5 Bedok South Road Singapore 469270 Singapore www.yokogawa.com/sg YOKOGAWA CORPORATION OF AMERICA 2 Dart Road Newnan GA 30265 USA www.yokogawa.com/us YOKOGAWA CHINA CO. LTD. 3F Tower D Cartelo Crocodile Building No.568 West Tianshan Road Changing District Shanghai, China www.yokogawa.com/cn YOKOGAWA EUROPE BV Euroweg 2 3825 HD AMERSFOORT The Netherlands www.yokogawa.com/eu YOKOGAWA MIDDLE EAST B.S.C.(c) P.O. Box 10070, Manama Building 577, Road 2516, Busaiteen 225 Muharraq, Bahrain www.yokogawa.com/bh IM 12X0X0-E-E Subject to change without notice Copyright © IM 12B6J1-41E-E Subject to change without notice Copyright © Yokogawa has an extensive sales and distribution network. Please refer to the European website (www.yokogawa.com/eu) to contact your nearest representative. Printed in The Netherlands, 00-000 (A) I Printed in The Netherlands, 03-1406