Buhler Technologies Installation and Operation Instructions Multi Component Gas Analyser BA 3 select

Analysentechnik Multi Component Gas Analyser BA 3 select Installation and Operation Instructions Original instructions BE550021 01/2017 Bühler Technologies GmbH, Harkortstr. 29, D-40880 Ratingen Tel. +49 (0) 21 02 / 49 89-0, Fax: +49 (0) 21 02 / 49 89-20 E-Mail: analyse@buehler-technologies.com Internet: www.buehler-technologies.com Bühler Technologies GmbH, Harkortstr. 29, D-40880 Ratingen Tel. +49 (0) 21 02 / 49 89-0, Fax: +49 (0) 21 02 / 49 89-20 Internet: www.buehler-technologies.com E-Mail: analyse@buehler-technologies.com Read this instruction carefully prior to installation and/or use. Pay attention particularly to all advises and safety instructions to prevent injuries. Bühler Technologies can not be held responsible for misusing the product or unreliable function due to unauthorised modifications. All rights reserved. Bühler Technologies GmbH 2017 Document information Document No...........................................................BE550021 Version.......................................................................... 01/2017 BA 3 select Contents 1 Introduction.....................................................................................................................................................................................................................  3 1.1 Intended Use.........................................................................................................................................................................................................  3 1.2 Equipment configuration .................................................................................................................................................................................  3 1.3 Scope of delivery ..................................................................................................................................................................................................  3 2 Safety instructions.........................................................................................................................................................................................................  4 2.1 Important notices................................................................................................................................................................................................ 4 2.2 General hazard warnings .................................................................................................................................................................................  5 3 Technical description ....................................................................................................................................................................................................  7 3.1 Configuration .......................................................................................................................................................................................................  7 3.2 Equipment overview .......................................................................................................................................................................................... 8 3.3 Gas flow diagrams .............................................................................................................................................................................................. 9 3.4 Measuring principles for oxygen measurement .....................................................................................................................................  10 3.4.1 Measuring principle of a zirconium dioxide cell....................................................................................................................... 10 3.4.2 Measuring principle of an electrochemical cell ......................................................................................................................... 11 3.4.3 Measuring principle of a paramagnetic cell ............................................................................................................................... 11 3.5 Technical Data....................................................................................................................................................................................................  14 4 Transport and storage ................................................................................................................................................................................................  16 5 Installation and connection ....................................................................................................................................................................................... 17 5.1 Installation site requirements........................................................................................................................................................................ 17 5.2 Installation ........................................................................................................................................................................................................... 17 5.2.1 Sample gas conditioning..................................................................................................................................................................  17 5.2.2 Specific measuring cell requirements.......................................................................................................................................... 18 5.2.3 Gas connections .................................................................................................................................................................................. 19 5.2.4 Electrical connections.......................................................................................................................................................................  20 6 Initial operation............................................................................................................................................................................................................ 24 6.1 Process .................................................................................................................................................................................................................. 24 6.2 Overview of key factory settings...................................................................................................................................................................  25 7 Operation and Control................................................................................................................................................................................................ 26 7.1 Menu overview and operating principle.................................................................................................................................................... 26 7.1.1 General information for navigating the menu ........................................................................................................................  28 7.2 Menu > Diagnostics .......................................................................................................................................................................................... 30 7.2.1 Menu > Diagnostics > Failure Log.................................................................................................................................................  30 7.2.2 Menu > Diagnostics > Service Log..................................................................................................................................................  31 7.2.3 Menu > Diagnostics > Status...........................................................................................................................................................  31 7.2.4 Menu > Diagnostics > Analysis ....................................................................................................................................................... 32 7.3 Menu > Base Settings.......................................................................................................................................................................................  32 7.3.1 Menu > Base Settings > Passwords ............................................................................................................................................... 33 7.3.2 Menu > Base Settings > Language................................................................................................................................................. 33 7.3.3 Menu > Base Settings > Pressure Sensor ....................................................................................................................................  34 7.3.4 Menu > Base Settings > Date/Time..............................................................................................................................................  34 7.3.5 Menu > Base Settings > Pumps ...................................................................................................................................................... 35 7.4 Menu > Channel Settings................................................................................................................................................................................  35 7.4.1 Menu > Channel Settings > Meas. Range ...................................................................................................................................  36 7.4.2 Menu > Channel Settings > Limits................................................................................................................................................. 37 7.4.3 Menu > Channel Settings > Outputs ............................................................................................................................................ 37 7.4.4 Menu > Channel Settings > Units .................................................................................................................................................  38 7.4.5 Menu > Channel Settings > Damping .........................................................................................................................................  39 7.4.6 Menu > Channel Settings > Adjustment ....................................................................................................................................  39 7.5 Menu > Calibration........................................................................................................................................................................................... 39 7.5.1 General information......................................................................................................................................................................... 40 7.5.2 Menu > Calibration > Period ........................................................................................................................................................... 41 7.5.3 Menu > Calibration > Deviation....................................................................................................................................................  42 7.5.4 Menu > Calibration > Auto .............................................................................................................................................................  42 7.5.5 Menu > Calibration > Manual........................................................................................................................................................  43 7.5.6 Menu > calibration > Logbook .......................................................................................................................................................  44 BE550021 ◦ 01/2017 Bühler Technologies GmbH i BA 3 select 8 Service..............................................................................................................................................................................................................................  45 8.1 Service schedule................................................................................................................................................................................................. 45 8.2 Leak test ..............................................................................................................................................................................................................  46 8.3 Replace filter element ...................................................................................................................................................................................... 47 8.4 Replacing the EC cell......................................................................................................................................................................................... 47 8.5 Cleaning ..............................................................................................................................................................................................................  48 8.6 Replacing fuses .................................................................................................................................................................................................  48 9 Service and repair......................................................................................................................................................................................................... 49 9.1 Status messages and troubleshooting ......................................................................................................................................................  49 9.1.1 Service Log messages........................................................................................................................................................................  49 9.1.2 Failure Log messages........................................................................................................................................................................  50 9.1.3 Calibration Log messages ................................................................................................................................................................  51 10 Disposal ...........................................................................................................................................................................................................................  52 11 Appendices.....................................................................................................................................................................................................................  53 11.1 Spare parts ..........................................................................................................................................................................................................  53 11.2 Service list ............................................................................................................................................................................................................ 54 12 Attached documents ...................................................................................................................................................................................................  55 ii Bühler Technologies GmbH BE550021 ◦ 01/2017 BA 3 select 1 Introduction 1.1 Intended Use The BA 3 select multi-channel gas analyser is used to continuously measure the gas concentration in industrial process gas, such as: – Monitoring exhaust gas concentration and optimising firing or combustion processes – Monitoring process flows – Mixing, producing and processing industrial gas The device must not be used – To analyse combustible, inflammable or explosive gas mixtures, – In explosive areas and – For applications where equipment failure or malfunction puts persons in immediate danger. – To convey highly toxic gas. 1.2 Equipment configuration The order key indicates the configuration. Please refer to the nameplate for your equipment configuration. 1.3 Scope of delivery – Analyser – Product documentation – Connection/mounting accessories (optional) BE550021 ◦ 01/2017 Bühler Technologies GmbH 3 BA 3 select 2 Safety instructions 2.1 Important notices This unit may only be used if: – The product is being used under the conditions described in the operating- and system instructions, used according to the nameplate and for applications for which it is intended. Any unauthorized modifications of the device will void the warranty provided by Bühler Technologies GmbH, – Complying with the specifications and markings in the type plate, – Complying with the limits specified in the data sheet and the instructions, – Service and repair work not described in these instructions are performed by Bühler Technologies GmbH, – Using genuine replacement parts. These operating instructions are a part of the equipment. The manufacturer reserves the right to change performance-, specification- or technical data without prior notice. Please keep these instructions for future reference. Please particularly note the following analyser instructions: – Always transport the equipment diligently and carefully. Strong impact and shock may damage the measuring cells in the analyser or shorten their life! – Avoid condensation inside the equipment, as the measurement system could be damaged and become defective. If the sample gas contains condensable components, the analyser must have suitable upstream sample gas conditioning. Our customer service will gladly help you select a system. Signal words for warnings DANGER Signal word for an imminent danger with high risk, resulting in severe injuries or death if not avoided. WARNING Signal word for a hazardous situation with medium risk, possibly resulting in severe injuries or death if not avoided. CAUTION Signal word for a hazardous situation with low risk, resulting in damaged to the device or the property or minor or medium injuries if not avoided. NOTICE Signal word for important information to the product. Warning signs In this manual, the following warning signs are used: Warning against hazardous situations General notice Warning against electrical voltage Disconnect from mains Warning against respiration of toxic gases Wear respirator Warning against acid and corrosive substances Wear eye/face protection Warning against potentially explosive atmospheres Wear protection gloves Warning against hot surface 4 Bühler Technologies GmbH BE550021 ◦ 01/2017 BA 3 select 2.2 General hazard warnings The equipment must be installed by a professional familiar with the safety requirements and risks. Be sure to observe the safety regulations and generally applicable rules of technology relevant for the installation site. Prevent malfunctions and avoid personal injuries and property damage. The operator of the system must ensure: – Safety notices and operating instructions are available and observed, – Inspections prior to initial operation and routine inspections according to the Ordinance on Industrial Safety and Health (BetrSichV) are performed, – The respective national accident prevention regulations are observed, – The permissible data and operational conditions are maintained, – Safety guards are used and mandatory maintenance is performed, – Legal regulations are observed during disposal. Transport – Always transport the BA 3 select with care. Strong impact and shock may damage the measuring cells in the analyser or shorten their life! Sample gas conditioning – Prevent condensation or particles inside the unit as the measuring system may become defective. If the sample gas contains condensable components, the BA 3 select must have suitable upstream sample gas conditioning. Suitable filters must be installed ahead of the unit’s gas inlet. Our customer service will gladly help you select a sample gas conditioner. Maintaining the device parameters – Be sure to maintain the approved operating and ambient temperatures and the technical specifications. Personnel – The unit must only be installed, operated and maintained by qualified personnel. Maintenance, Repair Please note during maintenance and repairs: – Repairs to the unit must be performed by Bühler authorised personnel. – Only perform conversion-, maintenance or installation work described in these operating and installation instructions. – Always use genuine spare parts. Always observe the applicable safety and operating regulations in the respective country of use when performing any type of maintenance. DANGER Electric voltage Risk of electric shock a) Disconnect all poles of the unit from the mains for any maintenance on electric components. b) Secure the equipment from accidental restarting. c) The unit may only be opened by trained, competent personnel. d) Ensure the correct voltages supply. DANGER Toxic, corrosive gases The measuring gas led through the equipment can be hazardous when breathing or touching it. a) Check tightness of the measuring system before putting it into operation. b) Take care that harmful gases are exhausted to a save place. c) Before maintenance turn off the gas supply and make sure that it cannot be turned on unintentionally. d) Protect yourself during maintenance against toxic / corrosive gases. Use suitable protective equipment. BE550021 ◦ 01/2017 Bühler Technologies GmbH 5 BA 3 select DANGER Potentially explosive atmosphere Explosion hazard if used in hazardous areas. The device is not suitable for operation in hazardous areas with potentially explosive atmospheres. Do not expose the device to combustible or explosive gas mixtures. 6 Bühler Technologies GmbH BE550021 ◦ 01/2017 BA 3 select 3 Technical description 3.1 Configuration The BA 3 select is a gas analyser for 19” rack mounting with a modular design which can be equipped with three different oxygen measuring cells. Up to three parallel gas components can be measured. There are three different cells available for measuring oxygen: – Electrochemical O2 cell for measuring % – High-precision paramagnetic cells – Zirconium dioxide cell for measuring traces of oxygen Display and operation The analyser is standard equipped with a 4.3” touchscreen display. This display is used to show measurements and operate the unit. Front plate filter An optional microfilter is available for the front of the housing to filter particles from the sample gas flow. This requires no tools to change. A built-in safety filter is standard on all gas paths without front panel filter. Flow measurement The options for having the unit display the gas flow rate are: – Float flow meters on the front panel or – Bar graph in the display Gas pumps A pump conveying the sample gas through the unit may optionally be built into each analyser gas path. Channel markings The channels on the unit are marked as follows: Symbol Explanation O2-ZrOx Oxygen measurement via zirconium dioxide cell O2-EC Oxygen measurement via electrochemical cell O2-Para Oxygen measurement via paramagnetic cell Output signals For effective monitoring, all status, limit and alarm messages are output at the back of the unit in analogue and/or digital form (see chapter “Signal outputs [> page 20]"). Gas connections The respective number of gas path PVDF hose fittings are located at the back of the housing. Stainless steel bulkhead couplings are optional. (Note: Stainless steel bulkhead couplings are standard on ZrOx measuring cells.) Gas Flow Control The analyser is equipped with internal bypass controllers to keep the gas volume flowing through the cells as consistent as possible. This allows a high, stable sample gas flow to the analyser, hence short equipment response times. Valves for automatic calibration The unit may optionally be equipped with 3/2-way solenoid valves. These will automatically switch between the sample gas and calibrating gas input on the unit. Electric supply The electric supply is located at the back of the housing. BE550021 ◦ 01/2017 Bühler Technologies GmbH 7 BA 3 select Your equipment configuration Please refer to the nameplate on the unit and the explanation in chapter "Equipment configuration [> page 3])” for your specific equipment configuration. On start-up the unit will further show which measuring cells are installed and the software version. During operation you may view the configuration via Menu > Diagnostics > Status. 3.2 Equipment overview The following views explain the elements of the analyser. 1 2 3 4 Fig. 1: BA 3 select, front view 1 Touchscreen and measurement display 2 Sample gas filter (optional) 3 Flow meter, varies by number of channels 4 Service door (for optional EC cell) 7 1 2 3 4 5 6 Fig. 2: BA 3 select, rear view 1 gas in Sample gas input 4 RS232 RS232 port (optional) gas out Gas outlet 5 Fuse Fuse 1 cal. gas Calibrating gas inlet 6 Power 2 ST1 to ST4 Signal output Ch. 1 to Ch. 4 Power supply with built-in fuse and ON / OFF switch 3 ST04 Equipment status 8 Bühler Technologies GmbH 7 Fan BE550021 ◦ 01/2017 BA 3 select 3.3 Gas flow diagrams The analyser may be equipped with up to three O2measuring cells and three related, separate gas paths. The flow diagram below shows the equipment base version with one measuring cell or one channel. The flow diagrams may vary on units with multiple measuring channels (measuring points). A special flow diagram will then be included with your unit. Legend 1 3/2 way solenoid valve (optional with auto cal. function) 2 Internal pump for EC and paramagnetic cell 3 Flow regulator 4 Pressure sensor 5 Measuring cell 6 Flow meter (optional) 7 Internal pump for ZrOx cell Flow diagram Cal. Gas Sample gas 1 2 3 4 5 6 7 Pressure: With internal pump Max. 1200 mbar absolute Without internal pump Max. 1800 mbar absolute Flow (gas in): Cell flow: 120 L/h, constant due to internal pump ZrOx approx. 8 L/h, internal control Paramagnetic approx. 8 L/h, internal control EC approx. 12 L/h Tamb: 10 °C … 45 °C Tab. 1: Gas flow diagram for the equipment base version Sample gas or calibrating gas is assigned through the solenoid valve (optional) (1). The maximum pressure permitted at the gas inlet varies by version (see above). On the standard version a sample gas pump (2 or 7) built into the gas path produces a constant flow of approx. 120 L/h. The flow regulator (3) keeps the gas flowing through the measuring cell (5) consistent. On the version with controlled flow the flow through the unit can be set externally from 40 to 100 L/h. Again, the flow regulator ensures a consistent flow through the measuring cell. Excess gas flows off through the bypass. The cell flow must not exceed the value permitted for the cell (see above) and should be as consistent as possible. The barometric pressure sensor (4) compensates the results based on barometric variations. The flow meter (6, optional) or the optional bar graph in the display shows the gas flow through the measuring cell. BE550021 ◦ 01/2017 Bühler Technologies GmbH 9 BA 3 select 3.4 Measuring principles for oxygen measurement 3.4.1 Measuring principle of a zirconium dioxide cell The following illustration shows the configuration of a zirconium dioxide measuring cell. The measuring cell consists of a zirconium dioxide tube (1) with two platinum wire electrodes. Inside the tube the sample gas flows through is the measuring electrode (3). The electrode outside the tube serves as a reference electrode (4) with a constant electrode potential. The electrodes and the ceramic tube hence form a voltaic cell. Here the ZrO2 serves as a solid object electrolyte. To obtain favourable values for the oxide ion conductivity the measuring cell is heated to approx. 750 °C. A thermopile (5) on the measuring cell determines the actual measuring temperature T. An electronic control circuit ensures a constant cell temperature. 1 Zirconium dioxide tube 2 Ceramic cover for the reference electrode 3 Measuring electrode 4 Reference electrode 5 Thermal element 6 Reference electrode connecting wire 7 Measuring electrode connecting wire Sample gas The NERNST equation is the basis for determining the concentration of oxygen in gases by ZrO2 measuring cell. U= R∙T p O , air ln 4 F p O , sample gas 2 2 Where: U= R= T= F= p O2, air = p O2, sample gas Cell voltage in mV Molar gas constant; R = 8.31 J mol-1 K-1 Measuring temperature in K Faraday’s constant; F = 9.64 · 104 C mol-1 Partial pressure of the oxygen on the reference electrode in dry air in Pa = Partial pressure of the oxygen on the measuring electrode The calculation requires the total pressures on both electrodes to be about equal. In this case the volume concentration Ѱ corresponds with the partial pressure p. After solving (eq. I) with pO2, sample gas (or Ѱ O2, sample gas) and using the values for the constants R and F you will have the following conditional equation for the oxygen concentration in the sample gas in Vol.%: ѰO2, sample gas= 20.64 ∙ e -46.42 ∙ U/T 10 Bühler Technologies GmbH Where: Ψ O2, sample gas = e= U= T= 20.64 oxygen concentration of the sample gas in Vol.% Euler's number 2.7182… Cell voltage in mV Measuring temperature in K O2 concentration for air with a rel. humidity of 50 % in Vol.% BE550021 ◦ 01/2017 BA 3 select 3.4.2 Measuring principle of an electrochemical cell The electrochemical O2 measuring cell (EC cell), simplified, represents a battery. However, on the EC cell there will only be flow if the gas (O2) to be measured is present at the gas inlet. The cell consists of a cylindrical plastic housing which is closed with a gas permeable membrane (a) at the gas entry point. The housing is filled with a liquid electrolyte (acidic or alkaline solution) (c) where the gold measuring electrode (cathode) (b) and the lead counter-electrode (anode) (d) are located. e) f) d) c) a) b) O2 Fig. 3: Diagram of an EC cell a) Semi-permeable membrane b) Gold electrode c) Electrolyte d) Lead electrode e) Measuring resistance f) Thermistor With the external electric circuit closed, the lead electrode is oxidised and the oxygen in the sample gas reduced through the gold cathode. The lead electrode emits electrons to the external electric circuit, oxygen reacts with the H+ ions into water, absorbing the electrons. These spatially separate redox reactions produce current flow between the electrodes in the external electric circuit, proportional to the O2 content of the sample gas. The voltage drop (mV range) through the resistor (e) in the external electric circuit serves as the test signal. The thermistor (f) in the electrolyte compensates temperature influences. Four chemical reactions occur at the electrodes: Anode (2): 2Pb + 2H2O ⇒ 2PbO + 4H+ + 4e- Cathode (4): O2 + 4H+ + 4e- ⇒ 2H2O Brutto reaction: O2 + 2Pb ⇒ 2PbO Tab. 2: Table 2: REDOX reactions in the EC cell 3.4.3 Measuring principle of a paramagnetic cell The paramagnetic cell uses the distinct paramagnetic properties of oxygen to measure O2 concentration. Due to this property the O2 molecules are greatly drawn toward increasing magnetic field intensity. On the other hand, virtually all other gases have diamagnetic properties and are pushed away from a magnetic field. This results in the extraordinarily high selectivity of this oxygen measurement process. A permanent magnet with wedge-shaped pole shoes (a) produces a highly non-homogeneous magnetic field inside the measuring cell. A freely rotatable handle made up of glass balloons (c) and a torsion strap (b) is suspended between these pole shoes. The balloons are filled with nitrogen, which has slightly diamagnetic properties. A wire loop is located around the handle. At the middle of the handle is a small mirror (d). It directs the light from an LED (e) to a photocell (f). BE550021 ◦ 01/2017 Bühler Technologies GmbH 11 BA 3 select Fig. 4: Schematic diagram of a cell a Permanent magnet with pointy pole shoes d Mirror b Torsion strap e LED c Nitrogen-loaded glass handle f Photocell If oxygen enters the chamber, the O2 molecules are drawn toward the increasing magnetic field force. The magnetic field at the ends of the poles increases. As a result, the nitrogen loaded handle is forced out of the magnetic field and the torsion strap turns with the mirror. This changes the light influx, hence the voltage at the photocell. This changes the current flow in the wire loop. The induced magnetic moment of this live loop resets the handle to the zero position. The compensation current measured in the wire loop is proportional to the oxygen concentration and serves as a measurement signal. 3.4.3.1 Carrier gas factor Carrier gases are gas components found in the sample gas in addition to the actual component being measured. Depending on the measuring method these components can interfere with the measurement, resulting in false measured values. To minimise this effect, relevant carrier gases can be added to the calibrating gas (zero gas and span gas) at a concentration which will later occur in the sample gas. This will calibrate out the carrier gas influence. 3.4.3.2 Adjustments for carrier gases In a paramagnetic cell the very high magnetic susceptibility of oxygen is utilised to detect it. This measuring method is extremely selective, since other gases in the sample gas flow typically have a low magnetic susceptibility, so their impact on the measurement values is negligible. However, measuring errors could occur if the device was calibrated using O2+N2 as the span gas but very high concentrations interfering carrier gases are later present during measurement. In this case, significant measurement errors will occur (also see examples below). Since calibrating gases typically do not contain the carrier gases, an adjustment value can at least allow for this effect from a calculation perspective. The respective values are listed in table "Adjustments β for common carrier gases (values for other gases upon request) [> page 13]". These β values correspond with the unit’s zero point deviation if all of the volume flow through the unit consists of the carrier gas listed. Adjust the measured O2 concentration using the formula C = Cmeas– Cadj With Cadj= (βadj,1 x Ccarrier,1 + βadj,2 x Ccarrier,2 +…+ βadj,n x Ccarrier,n) and C Cadj Cmeas Ccarrier,1…n βadj,1…n 12 Adjusted O2 volume concentration Total adjusted value Measured (unadjusted) O2 volume concentration Volume concentration of carrier gas components 1 to n Adjustment factor from table 1 for the 1st to nth carrier gas component Bühler Technologies GmbH BE550021 ◦ 01/2017 BA 3 select Example 1: Calibration conditions: - Ambient temperature Ta = 50 °C 20.9% O2 in N2 - (O2 + N2) as span gas Sample gas: 0 % O2 Carrier gas: 100% CO2 Measurement result: C meas -0.29 % O2 Adjustment: C adj,CO2 = 100 * -0.0029 = -0.29% Adjusted result: C = C meas – C adj = -0.29 % – (-0.29%) = -0.29 % + 0.29 % = 0 Example 2: Calibration conditions: Ambient temperature Ta = 50 °C with N2 as zero gas (O2 + N2) as span gas Sample gas: 2 % O2 98 % carrier gases: 10% CO2 + 5% CO + 5% NO + 78% N2 Measurement result: C meas 4.13 % O2 10 % CO2 C adj,CO2 = 10 x (-0.0029) = -0.029 5 % CO C adj,CO = 5 x (+0.0007) = +0.004 5 % NO C adj,NO = 5 x (+0.4296) = 2.150 78 % N2 C adj,N2 = 78 x (00.00) = 0.00 Total: Cadj= C adj,CO2 + Cadj,CO + Cadj,NO + Cadj,N2 = +2.125 ≈ +2.13 Adjusted result: C = C meas – C adj = 4.13 – 2.13 = 2 % O2 Adjustments: Gas Formula β adj (at Ta=20°C) β adj (at Ta= 50°C) Acetylene HCCH -0.0025 -0.0028 Ammonia NH3 -0.0017 -0.0019 Benzol C6H6 -0.0124 -0.0136 Nitrous oxide N2O -0.0020 -0.0022 Ethanol C2H5OH -0.043 -0.047 Ethyl acetate CH3COOC2H5 -0.122 -0.134 Ethylene C2H4 -0.020 -0.022 Helium He +0.0029 +0.0032 Carbon dioxide CO2 -0.0026 -0.0029 Carbon monoxide CO +0.0006 +0.0007 Methane CH4 -0.0016 -0.0017 Ozone O3 +0.0054 +0.0060 Hydrogen sulphide H2S -0.0039 -0.0043 Nitrogen N2 0 0 Nitrogen dioxide NO2 +0.05 +0.16 Nitric oxide NO +0.4256 +0.4296 Hydrogen H2 +0.0023 +0.0026 Tab. 3: Adjustments β for common carrier gases (values for other gases upon request) If the cell temperature deviates from the Ta values, you can obtain values between 20 °C and 50 °C by linear interpolation of the adjustments βadj. The paramagnetic cell is factory thermostated to 50 °C. Therefore use the values βadj at Ta = 50 °C. If you’re unsure if your paramagnetic cell is thermostated, please contact our technical service (see chapter "Service and repair [> page 49]"). BE550021 ◦ 01/2017 Bühler Technologies GmbH 13 BA 3 select Automatic carrier gas adjustment for paramagnetic cell: You can enter the adjustment in the analyser so you will not always have to manually subtract the O2 adjustment from your measurement value (see chapter "Menu > Channel Settings > Adjustment [> page 39]"). The analyser will then continuously subtract this adjustment from the measurement value and always display the adjusted measurement value. 3.5 Technical Data General Housing Electric supply Ambient parameters Dimensions: 19" rack mount housing, 3 HE H x W x D, style 1: 132 x 440 x 425 mm H x W x D, style 2: 132 x 440 x 335 mm Protection class: IP 20 Weight: max. 7 kg Display and control: 4.7" touchscreen display Voltage: 230 V AC or 115 V AC (note nameplate on the unit) Mains frequency: 50/60Hz Max. power input: 60 W Ambient temperature: 10 °C … 45 °C Relative humidity: < 75 % Ambient pressure: 875 mbar to 1200 mbar Transport and storage temperature: 5 °C - 65 °C AUTO cal. function Optional for each measuring channel: Zero gas (air) + span gas Warm up time Minimum 30 min (up to 2 h recommended for high-precision measurements) Sample gas connections Gas paths Inlet parameters Max. three separate gas paths (with auto cal. function) Screw-in connection: Swagelok 6 mm PVDF for 4/6 tube Gas inlet temperature: 5 °C to 50 °C Sample gas pressure (absolute): 875 mbar to max. 1800 mbar, reduced to max. 1200 mbar with internal pump Sample gas conditioning: purified/ filtered (<15 µ filtration) sample gas with dew point < 10 °C (always 5 K below ambient temperature). Signal inputs and outputs Analogue output: 0-20 mA / 4-20 mA / 0-10 V / 2-10 V inside unit variable by channel Limit relay: 2x per measuring channel (125 V AC, 0.5 A / 30 V DC, 1 A) Status relay: Error, service, calibration, measuring range (125 V AC, 0.5 A / 30 V DC, 1 A) Binary inlets: 1x per channel + 2 x per unit: designed for 24V, potential-free 24 Volt output: 1x per channel (for supply binary inputs), protected by T250mA Serial port: RS 232 14 Bühler Technologies GmbH BE550021 ◦ 01/2017 BA 3 select Parts in contact with sample gas Component Materials in contact with media Pump PET, PPS Flow regulator PTFE, stainless steel (1.4571) Gas lines FPM (Viton), stainless steel (1.4571) Solenoid valves PVDF or stainless steel (1.4571) Gas ducts PVDF or stainless steel (1.4571) Flow meter PVDF, borosilicate glass Measuring cell ZrOx cell Paramagnetic cell EC cell 1.4571, ZrOx ceramic 1.4401 Borosilicate glass Platinum-iridium alloy ABS ZrOx cell* Paramagnetic cell EC cell Largest measuring range (MR) 0-10000 vpm (0-21 Vol.%)** 0-100 % 0-25 % Smallest measuring range 0-10 vpm 0-1 % 0-10 % Response time t90*** < 4 sec < 5 sec < 15 sec Linearity deviation < 1 % FS (< 2 % FS within the smallest MR) < 0.2 Vol.% < 1 % FS Zero drift < 1 % FS /week < 0.2 Vol.% /week < 2 % FS /week Measurement value drift < 0.3 % FS / week < 0.2 % MW /week < 2 % FS /week Repeatability 1 % FS (2 % within the smallest MR) 1 % FS 1 % FS Detection limit 0.1 vpm within MR 0-10vpm 0.1 % 0.2 % Pressure compensation optional yes yes Thermal stabilisation yes yes - Measuring cells Measuring cell * Two cell types available: (A) catalytically active cell (CAC) => not for flammable carrier gases. (B) catalytically inactive cell => suitable if traces of flammable gases are present (< 10 vpm H2, CO, CH4) ** Optional for unit with modified calibration routine *** Signal damping adjustable fr. 1 sec to 20 sec Abbreviations: FS …from span MW …from measurement r.F. …relative error BE550021 ◦ 01/2017 Bühler Technologies GmbH 15 BA 3 select 4 Transport and storage Transport The unit is sensitive to shock and vibration. Therefore, where possible, transport in the original packaging or large, sturdy packaging at a minimum consisting of 3 layer carton, plastic or aluminium sheet. Line the inside of the packaging with padding at least 10 cm thick on all sides. The unit should be marked fragile for shipping. Removal from service and storage Purge the unit with dry nitrogen or dry air before removing from service for extended periods. Then close the gas inputs and outputs to prevent dirt, dust and moisture from entering the unit. Store the unit in a dry, ventilated, dust-free room. Cover the unit with suitable packaging to protect it from liquids and dirt. Storage temperature: 5 °C … 65 °C 16 Bühler Technologies GmbH BE550021 ◦ 01/2017 BA 3 select 5 Installation and connection 5.1 Installation site requirements DANGER Potentially explosive atmosphere Explosion hazard if used in hazardous areas. The device is not suitable for operation in hazardous areas with potentially explosive atmospheres. Do not expose the device to combustible or explosive gas mixtures. 19” rack or tabletop: The unit is suitable for indoor use mounted in a 19” rack or as a tabletop unit. The unit must rest on support rails when installed in a 19” rack. The mechanical strain is too high when mounted solely via the front panel. Cooling: The unit is forced-air cooled via a fan at the back. To ensure air can circulate freely, maintain a distance to other objects or walls of at least 3 cm at the top and 10 cm at the back of the analyser. Dust: The unit must be set up in a low-dust environment. Otherwise dirt can accumulate inside the unit and in the long term result in malfunctions or failure. Shock: Select a preferably low-vibration site. Mechanical oscillation and vibration, particularly low frequency shock (e.g. from traffic or heavy equipment) can interfere with measurements, cause equipment errors or permanent damage. Ambient temperature: The approved ambient temperature of 5 °C to 45 °C must be maintained during operation. The measuring cells can optionally be thermostated or temperature compensated to max. 50 °C. This will largely compensate the effects of temperature fluctuations. Please refer to the key on the nameplate to determine whether your unit features automatic temperature compensation. Disturbance sources: No heat sources or equipment emitting strong magnetic fields (e.g. motors, transformers) may be located near the installation site. Even exposing the unit to sunlight for extended periods and the resulting temperature fluctuations can alter the measurement values. This also applies to severe temperature fluctuations and barometric variations. Regularly calibrate the unit, including after severe changes in the barometric pressure or temperature. 5.2 Installation The unit is delivered in cardboard packaging with filler material. The analyser measuring cells are sensitive to shock and vibration. Therefore, if possible, keep the original packaging for future analyser transport. Otherwise dispose of the packaging materials according to local regulations. Check the unit for any transport damage. Do not install the unit if it shows any type of damage. 19” rack mounting Place the analyser on support rails and secure the screws to the front face. 5.2.1 Sample gas conditioning To ensure the least possible interference and low analyser maintenance the gas inlet requirements (Technical Data) must be observed as consistently as possible. Further avoid dirt on any parts the sample gas flows through. Particularly important sample gas parameters are: – the gas moisture – the gas volume flow – the gas pressure – the gas temperature – the particle load in the gas flow – aggressive and/or gas components altering measurement value BE550021 ◦ 01/2017 Bühler Technologies GmbH 17 BA 3 select To ensure low maintenance, the analyser typically requires suitable upstream gas conditioning. This greatly affects the quality and correctness of your measurements. The complexity of the required gas conditioning will vary depending on the process and measuring task. In this context, it’s essential for calibrating gases to flow through the entire gas conditioning system for preferably identical pressure, temperature and flow ratios. This is the only way to compensate the gas conditioning possibly affecting the result. If the gas input and ambient conditions change considerably, always recalibrate the analyser (see chapter "Menu > Calibration"). NOTICE Control valve We recommend installing a control valve to adjust the gas flow upstream from the gas conditioning system. Installation in the sample gas output will increase the pressure in the analyser and possibly result in measuring errors. Damping vessel If rapid, high fluctuations of pressure or flow occur in the gas lines (inlet or outlet) we recommend using a damping vessel (> 0.5 L) upstream from the gas inlet. Please feel free to discuss your specific measuring task with our customer service. Our knowledgeable and experienced staff will be able to recommend modified gas conditioning. 5.2.2 Specific measuring cell requirements ZrO2 measuring cell – If the sample gas contains reducing components (e.g. alcohols), install an active carbon filter upstream from the analyser. This will prevent undesirable chemical reactions at the Pt electrodes in the cell which will falsify the measurement values. – Do not convey aggressive sample gas containing high concentrations of halogen, sulphurous gases (e.g. SO2) or phosphorous and siliceous gases through the analyser. These types of gases will damage the measuring cell. – Always use stainless steel tubes as the gas lines for measuring oxygen concentrations below 100 ppm. The O2 permeability of plastic lines may otherwise significantly alter the measurement values. Particularly ensure all joints in the line system are tight. – Keep the sample gas paths as short as possible to avoid a shift in the chemical balance along the way. EC measuring cell – High amounts (> 1 Vol.%) of ammonia, SO2, hydrogen chlorides or benzol compounds can significantly alter the measurement values. If these substances are present, the calibrating gas used should contain the same concentration of these interfering components to be expected during measurement. This will calibrate out this interfering factor to the greatest possible extent. – Please further ensure the sample gas conveyed does not fall below the dew point of 4°C. If sample gases are too dry, the cell can lose electrolyte, damaging the cell. Paramagnetic cell – When using this measuring cell, pay particularly attention to low-vibration, shockproof installation. Otherwise the measurements may be significantly altered or the cell damaged. – Reduce fluctuations in the pressure and flow in the sample gas lines upstream and downstream from the analyser. Vibration may otherwise be induced in the handle, which will also alter the result. – Cross-sensitivity to carrier gases is typically very low. Only extremely high concentrations of carrier gases will alter the results (also see chapter "Carrier gas factor [> page 12]"). 18 Bühler Technologies GmbH BE550021 ◦ 01/2017 BA 3 select 5.2.3 Gas connections DANGER Toxic, corrosive gases The measuring gas led through the equipment can be hazardous when breathing or touching it. a) Check tightness of the measuring system before putting it into operation. b) Take care that harmful gases are exhausted to a save place. c) Before maintenance turn off the gas supply and make sure that it cannot be turned on unintentionally. d) Protect yourself during maintenance against toxic / corrosive gases. Use suitable protective equipment. When connecting gas lines to the unit, please note: – The connection must be made by a qualified professional. – The substances selected (particularly chemical, thermal and pressure-resistance) must be suitable for the measurement task. Corrosive gases will significantly reduce the life of the measuring cells. – Limit rapid pressure fluctuations in the gas inlet and outlet pipes to prevent a fluctuation in the measurement values. If rapid, high fluctuations of pressure or flow occur in the gas lines we recommend using a damping vessel (> 0.5 L) upstream from the gas inlet. – Suitable sample gas conditioning is required upstream from the analyser. – If the gas inlet or ambient conditions change considerably, always recalibrate the analyser (see chapter "Menu > Calibration [> page 39]"). PVDF hose couplings for tubes with 4 mm inside diameter (6 mm outside diameter) at the back of the analyser are standard. If the analyser is equipped with stainless steel bulkhead couplings (optional), stainless steel tubes with 6 mm outside diameter may be connected gas tight. The back of the unit will have the respective number of gas connections and terminal strips for signal outputs based on the number of measuring channels. 7 1 2 3 4 5 6 Fig. 5: BA 3 select, rear view 1 gas in Sample gas input 4 RS232 RS232 port (optional) gas out Gas outlet 5 Fuse Fuse 1 cal. gas Calibrating gas inlet 6 Power 2 ST1 to ST4 Signal output Ch. 1 to Ch. 4 Power supply with built-in fuse and ON / OFF switch 3 ST04 Equipment status BE550021 ◦ 01/2017 7 Fan Bühler Technologies GmbH 19 BA 3 select 5.2.4 Electrical connections 5.2.4.1 Signal outputs Two or three 16-pin PHÖNIX plugs (ST0 to ST3) are located at the back of the analyser for the input and output signals. Plug ST4 may optionally be configured to signal the measuring range or the measuring range switchover. To prevent interference, the signal lines should be routed isolated from the power lines. Refer to the tables below for the plug configuration. Plug 0 Pin Function Description / Status 1 NC contact Operation 2 Common 3 NO contact Malfunction 4 NC contact Operation 5 Common 6 NO contact Service required 7 NC contact Measurement Common Common 8 Common 9 NO contact Zero gas calibration 10 PE 11 Common Protective earth 12 Switch solenoid valve or pumps (optional) 13 Start calibration (zero gas) Connection data Relay, max. switching power 125 V AC / 1 A or 60 V DC / 1 A Relay, max. switching power 125 V AC / 1 A or 60 V DC / 1 A Relay, max. switching power 125 V AC / 1 A or 60 V DC / 1 A PE 14 15 + 16 - 24 V DC voltage output Tab. 4: Plug 0, system connection, 16-pin PHÖNIX connection terminals Plug 1-4 Pin Function Description / Status 1 NC contact Limit 1 2 Common 3 NO contact 4 NC contact Limit Value 2 5 Common 6 NO contact 7 NC contact Measurement Connection data Relay, max. switching power 125 V AC / 1 A or 60 V DC / 1 A Relay, max. switching power 125 V AC / 1 A or 60 V DC / 1 A Relay, max. switching power 125 V AC / 1 A or 60 V DC / 1 A 8 Common 9 NO contact Range calibration 10 PE Protective earth PE 11 + 12 - Gas concentration analogue output; configured in device menu 4 – 20 mA 0 – 20 mA 0 – 10 V 2 – 10 V Start calibration (span gas) Controls also see Signal outputs [> page 21] 13 14 15 + 16 - 24 V DC voltage output Tab. 5: Plug ST1 to ST4, measuring channel 1 to 4, 16-pin PHÖNIX connection terminals The binary inputs (plug ST0: pin 11/12 and pin 13/14 as well as plug 1-4: pin 13/14) may be controlled internally or externally. The following illustrations show the connection options. 20 Bühler Technologies GmbH BE550021 ◦ 01/2017 BA 3 select Control 24 V DC internal Control 24 V DC external 5.2.4.2 RS232 port The RS-232 serial port can be used to connect a 9-pin SUB-D plug to transfer the error and status messages to a receiver. The transfer speed can be up to 115200 baud. We recommend a wire cross-section > 0.5 mm2 and a maximum cable length of 15 m at a baud rate of 19200 baud. If the transfer speed is slow, the line may be longer, for high transfer speeds the line must be shorter. RS232 Pin Description 1 N/C 2 TxD 3 RxD 4 N/C 5 GND 6 N/C 7 N/C 8 N/C 9 N/C Tab. 6: RS232, 9-pin SUB-D plug The following interface parameters may be configured: Parameter Value Baud rate 4800, 9600, 19200, 38400, 115200 baud adjustable Stop bits 1 Data bits 8 Parity None Handshake without The length of the transmission protocol is variable. All characters are transmitted in ASCII format. Every transmission ends with +. Depending on the number of registered cells, lines with the following values will be transmitted via the port every second, each separated by semicolon: Parameter Data string Description Channel no. #1… #4 always appears, measuring channel number Concentration unit xx.xx %, ppm, mg/m³ always appears, concentration measured + unit Calibration mode Zero during zero gas calibration Span during span gas calibration ---- During normal operation, no calibration mode CalOK following successful calibration CalErr following failed calibration ----- During normal operation (no calibration) LM1 appears when the limit is breached --- No limit exceeded LM2 appears when the limit is breached --- No limit exceeded Calibration status Limit value 1 Limit value 2 BE550021 ◦ 01/2017 Bühler Technologies GmbH 21 BA 3 select Alarm Maintenance request active measuring range always appears A if an alarm has been triggered ! Alarm was automatically reset - Alarm deleted from logbook W "W" for maintenance request ! Maintenance request was automatically reset - Maintenance request deleted from logbook MR1 Measuring range 1 active MR2 Measuring range 2 active Tab. 7: Transfer protocol structure Sample data protocol, unit with two measuring cells: #1; 20.89 % ; ______ ; LM1 ; ___ ; A ; _ ; MR1 #2; 15.89 ppm ; CalOK ; LM1 ; LM2 ; ! ; _ ; MR1 Tab. 8: Sample plain text transmission protocol Additional commands can be used to fetch the following information via the interface or to send commands. The commands must be completed with + : Command Response UF The failure logbook will be output in plain text UM The maintenance logbook will be output in plain text UC The calibration logbook will be output in plain text DF Deletes the first entry in the failure logbook DM Deletes the first entry in the maintenance logbook DC Deletes the first entry in the calibration logbook R Continue measurand output Tab. 9: Queries Sample logbook query: Input:UF Failure/Logbook: 1 Channel 3 22.08.16 13:18:46 Para Insufficient temperature 2 Channel 3 22.08.16 13:18:46 Para Heater defective 3 Channel 3 22.08.16 13:18:46 Para T-Sensor defective 4 Channel 1 22.08.16 13:18:59 ZrOx Heater defective 5 Channel 1 22.08.16 13:19:06 ZrOx temperature insufficient 6 Channel 1 22.08.16 13:19:10 ZrOx Limit 1 underrun 7 Channel 1 23.08.16 13:06:05 ZrOx temperature insufficient 8 Channel 1 23.08.16 13:06:05 ZrOx Limit 1 underrun 9 Channel 3 23.08.16 13:06:05 Para Insufficient temperature 10 Channel 3 23.08.16 13:06:06 Para T-Sensor defective 11 Channel 1 23.08.16 13:15:04 ZrOx Heater defective 12 Channel 3 23.08.16 13:15:05 Para Heater defective Tab. 10: Sample query logbook 22 Bühler Technologies GmbH BE550021 ◦ 01/2017 BA 3 select 5.2.4.3 Power supply DANGER Electric voltage Risk of electric shock if the unit is connected to the supply incorrectly. a) The unit must be connected by trained, expert personnel. b) Ensure the correct supply voltage. c) Only use the included power cord or a power cord with the specifications indicated. The supply voltage is 230 V AC 50/60 Hz or 115 V AC 50/60 Hz. Verify the available mains voltage matches the required supply voltage per the nameplate. Use the included power cable to connect the analyser to the DIN EN 60320-2-3 connector at the back marked “power”. BE550021 ◦ 01/2017 Bühler Technologies GmbH 23 BA 3 select 6 Initial operation 6.1 Process Preparation Please ensure – The unit was assembled and connected properly. Particularly ensure the voltage supply and the gas connection are correct. – The gas conditioning system is working properly, – The zero gas has an oxygen concentration of 20.9 Vol.% and – The span gas supplied has the correct concentration (adapted to the measuring range). Switching on Switch on the analyser with the power switch at the back. After the Bühler logo the initialisation screen will display the equipment configuration: Initialization: BA 3 select Version: 1,0 Cells: ZrOx/EC – Software Version Rem. Time: – Installed measuring cells 15 min – As well as the remaining initialization time During initialisation you may touch the display to switch to measurement view, e.g. to configure the unit. The initialization progress is also displayed in measurement view:  WU 15 min  flashing O2-ZrOx: 0 20 19,3% 0 30% O2-EC: 21,2% 25% 0 0l/h Menu After initialization (standard 30 min) the measurement screen will appear. Here, use  Menu  to open the main menu or  Cal.  to go straight to calibration. Cal. O2-ZrOx: WU 15 min 0 20 19,3% 0 30% O2-EC: 21,2% 25% 0 0l/h Menu Cal. Wait at least 30 minutes for the unit to warm up, then perform the first calibration. To measure very low concentrations it may be helpful to allow the unit to continue to warm up, up to 2 h. After calibration the unit may be charged with the respective sample gas. Please observe the permissible gas inlet conditions. To ensure correct operation, the sample gas flow for the respective measuring cell should be set to the values in table "Gas flow diagram for the equipment base version [> page 9]". If the minimal flow rates are underrun, the measurement will be rejected and an error message will appear. You may now want to configure the analyser settings to your needs. A table with key settings can be found in the next chapter. If your unit has internal sample gas pumps, these can now be activated under  Menu  >  Base settings  >  Pumps. 24 Bühler Technologies GmbH BE550021 ◦ 01/2017 BA 3 select 6.2 Overview of key factory settings Check if the factory settings are suitable for your measurement task. If necessary, change them as described in chapter "Operation and Control". The following table lists the key parameters: Menu item Submenu Channel Settings Measuring ranges Meas. range MR1 and MR2 (customer-specific per order) Factory Setting Auto Switchover: OFF Limits No limit presets Outputs – Analogue outputs: 4-20 mA / on cal.: current value / on error: current value – RS 232 (optional): Baud rate: 4800, parity: no stop bits: 1 Base settings Adjustment No carrier gas adjustment set (Value 0) Damping For all measuring cells 1 sec (time constant) Units Custom, as ordered Language For delivery to Germany "German". For delivery to other countries "English". Passwords Password 1: 111 Password 2: 222 Pumps If applicable: Off Date / Time Date: Day.Month.Year, current date Time: hh:mm:ss current time CET (h:min) Calibration Pressure sensor (optional) Not set (pressure sensor calibrated prior to delivery) Auto Off / Time Period: 24 h Manual No preset Deviation Span gas: 10% from setpoint / zero gas: 1 Vol. % O2 fixed Period – Calibration period: 2 min – Purging Time: 5 min Check if the factory settings are suitable for your measurement task. If necessary, change these as described in chapter "Menu > Base Settings [> page 32]". BE550021 ◦ 01/2017 Bühler Technologies GmbH 25 BA 3 select 7 Operation and Control NOTICE The device must not be operated beyond its specifications. 7.1 Menu overview and operating principle The analyser is controlled via the touch display. NOTICE Delicate display The touch display is delicate. Do not use sharp or pointy objects such as pens, screwdrivers, etc. to operate it. Use the  Menu  button to access the main menu. Use the  Cal.  button to access the calibration submenu directly. Start a submenu by pressing the respective button. Use the  Meas  button to exit from the menu level and return straight to the measurement display. All parameters are protected from unauthorised access with a 3 character password. The default passwords at the time of delivery are:  Password 1 111  Password 2 222 The following menus are available for parametrisation and diagnostics: 26 Bühler Technologies GmbH BE550021 ◦ 01/2017 BA 3 select Main menu Submenu 1 Submenu 2 Cal Display Menu PWD 1 Enter Diagnostics Status For each cell (Actual status): Cell temp, cell signal, status, p-compensation PWD 1 Enter Logbook / Failures Logbook / maintenance Analysis Channel Settings Measuring ranges Limits Outputs Adjustment Damping Units Base Settings Language Error list PWD 1 Enter PWD 1 Enter PWD 2 Enter PWD 2 Enter PWD 2 Enter PWD 2 Enter PWD 2 Enter PWD 2 Enter PWD 1 Enter Maintenance request list Selection: Averages, characteristics (curve) MR: set manually or auto switch-over Sets two alarm limits per channel Setting analogue outputs & RS232 Interfering gas correction for paramagn. O2 cell Setting damping time constant for measuring signals Measuring unit options: ppm, % Language options: German, English PWD 2 Enter Passwords Change password 1 / password 2 PWD 1 Enter Pumps On / Off / On during calibration PWD 1 Enter Date / Time Setting the date & time PWD 2 Enter Pressure sensor Calibration Auto Manual Deviation Period Cal logbook Current pressure value + pressure sensor adjustment PWD 2 Enter PWD 2 Enter PWD 2 Enter PWD 2 Enter PWD 1 Enter Cycle time, zero gas-, span gas concentration, On/Off Manually execute cal. (zero-, span gas) Determines the allowed dev. from the cal. target value Setting cal. duration and sample gas flushing time Calibration history (with date/time) Fig. 6: BA 3 select menu overview BE550021 ◦ 01/2017 Bühler Technologies GmbH 27 BA 3 select 7.1.1 General information for navigating the menu Measurement screen The normal mode the analyser will show the measurement screen. It will show: – the current measurement value of each cell as a bar graph and as a measurement value in the specified unit O2-ZrOx: 19,1% A 0 0 20 25% 21,1% O2-EC: 25% – the measuring range 0 – a bar graph of the flow through the unit (channel 1) (optional) 0l/h Menu Cal. – the keys  Menu  and  Cal.  used to jump directly to the main or calibration menu. Flashing symbols A flashing icon in the measurement screen indicates a problem. Where:  A An event (alarm or error) was detected and recorded in the "Failure" log. The event may apply to one channel or the entire unit. °!°, An event (failure or alarm) occurred but was automatically reset. This is for example the case if a low temperature alarm is temporarily triggered. In this case an entry will be made in the failure log.  W Service is required. A "Service" log entry has been generated. The symbols will remain active until the associated log entries have been deleted. Learn how to open the respective log in chapter "Menu > Diagnostics [> page 30]" or "Menu > Calibration [> page 39]". Opening the submenu Navigate the menu with the respective button (key). To e.g. change the unit the gas concentration is displayed in, press  Menu  >  Channel Settings  > O2-ZrOx: 19.1% A O2-EC: 21.1% 0 0 20 25% Diagnostics Channel Settings Base Settings Calibration 25% 0 0l/h Menu Meas Cal.  Units Channel Settings Units: Measuring range Limits Outputs Units 02-ZrOx Display Vol. % Damping Meas 28 Bühler Technologies GmbH Esc. Meas Esc. BE550021 ◦ 01/2017 BA 3 select Extra buttons In addition to the buttons, the menus may also have extra buttons: The buttons # on the context: and $ Auto Calibration: have different functions depending 02-ZrOx Zero Gas 20,9 % Span Gas 0.1 % Off – Selecting the measuring cell or  All Channels Time Period – Browsing a list 10:00:00 h Esc. Meas – Browsing a selection Pressing a  button  – will open the respective submenu, – will open a keyboard to enter values – will highlight the button (inverted display). With a button highlighted, use the # and $ keys to browse the drop-down menu. To change a parameter, you will first need to press again to deselect the button. Be sure to save the changes with 8 in the respective menu. Values are not automatically saved upon exiting. Use  Esc  to cancel the input at any time. The next higher / previous screen will appear. Use  Meas  to return directly to the measurement screen. Parameter changes will not be saved! Entering values Use the on-screen keyboard to enter a value directly. Here you will see a keypad and context-specific extra keys (e.g.  : ,  , ,  <  or > ). MR1 You may correct the input with  C  or press  Esc  to cancel. Use the return key 8 0.0 Manual Settings: MR2 to apply the entry. 7 8 4 5 6 1 2 3 9 0 , Meas When entering an invalid value, an error message will appear (see example) and the respective parameter will not be changed. C Esc. Auto Calibration: Zero Gas Error Value incorrect Span Gas OK Time Period Esc. Meas Password Protect With password protect enabled, the analyser will require a password (1 or 2, see chapter "Menu overview and operating principle [> page 26]“) before a parameter can be changed. Diagnostics Failure Log Service Log Enter the password with the on-screen keyboard and press to confirm your input. 8 Please refer to chapter "Menu > Base Settings > Passwords“ for how to enable and disable password protect. BE550021 ◦ 01/2017 Password 1 7 8 4 5 6 1 2 3 9 0 Meas C Esc. Bühler Technologies GmbH 29 BA 3 select 7.2 Menu > Diagnostics The Diagnostics menu contains the following menu items:  Failure/ logbook This logbook lists all failures which have occurred including channel number, date, time and error message in plain text.  Maintenance/ logbook Outstanding service is recorded in the service log. Note: Not all service will be listed. Please also refer to chapter Service.  Status This menu shows the status of each measuring cell along with the cell voltage, cell temperature and the compensation type.  Analysis NOTICE Diagnostics Failure Log Status Service Log Analysis Meas Esc. This shows the average values – over 24 h and 1/2 h. The characteristics can also be displayed in a graph. Calibration Log The  Calibration  menu also contains a logbook with records on all calibrations. 7.2.1 Menu > Diagnostics > Failure Log This logbook records all alarms and errors. If this logbook has an entry, the measurement display will flash  A  or  !  at the respective channel. Up to 40 messages can be saved. On the 41st entry the oldest message will automatically deleted and overwritten with the new message. The  !  will appear if the event was reset without user interaction, e.g. for a low temperature alarm. Failure Log Open the logbook using  Menu  >  Diagnostics  >  Failure Log  and enter the password. Diagnostics Failure Log Status Service Log Analysis Meas Esc. The screen will show the following information: Failure Log – Messages displayed / total messages 1. Ch. 1 -- 08.01.15 12:04:11 ZrOx Limit 2 overrun – Current time 2. Ch. 1 -- 07.01.15 19:04:21 ZrOx Limit 1 underrun – Always 3 messages in plain text 3. Ch. 1 -- 05.01.15 09:05:48 ZrOx Limit 2 overrun Use the $ and # 1-3/6 14:42:51 buttons to browse the list. Take the action required by the respective message. You will find information about this in chapter "Status messages and troubleshooting [> page 49]“ and others. Meas Del Esc. Use the  Del  key to delete the top (oldest) message (always no. 1). Once all messages have been deleted, the marker  A  or  !  after the respective measurement display will disappear. 30 Bühler Technologies GmbH BE550021 ◦ 01/2017 BA 3 select 7.2.2 Menu > Diagnostics > Service Log This logbook lists the required service. If an entry exists, the measurement channel will flash  W  at the respective channel. Service Log Use  Menu  >  Diagnostics  >  Service Log  to open the logbook and enter the password. Diagnostics Failure Log Status Service Log Analysis Meas Esc. The screen will show the following information: Service Log – Messages displayed / total messages 1. 16.01.15 86:45:19 20,000 operating hours 1-1/1 18:37:35 – Current time – Always 3 messages in plain text Use the $ and # buttons to browse the list. Meas Del Esc. Use the  Del  key to delete the top message (always no. 1). Once all messages have been deleted, the  W  after the respective measurement display will disappear. For information for any required service, refer to chapter "Service". NOTICE Service schedule Not all required service is indicated in the logbook. Please also follow the service schedule in chapter "Service". 7.2.3 Menu > Diagnostics > Status This menu provides an overview with the status of each measuring cell. Status Open  Menu  >  Diagnostics  >  Status  and enter the password. Diagnostics Failure Log Status Service Log Analysis Meas Select the respective channel with the buttons # and $ . It will show: – the measuring cell, – the status:  OK ,  A ,  !  or  W  Alarm messages will appear before maintenance messages. Esc. Status 02-ZrOx Status: A Time signal: -1.2mV Cell Temperature: 749.9 °C Compensation: Press. Meas 19.1% Esc. Note: If a status other than  OK  appears, please refer to the respective logbook. In particular, the EC cell must be replaced if worn (also see chapter 8.4) – the cell temperature – the compensation type BE550021 ◦ 01/2017 Bühler Technologies GmbH 31 BA 3 select 7.2.4 Menu > Diagnostics > Analysis The characteristics are continuously analysed. The system records – the average value over the past 30 min (1/2 h average value) – the average value over the past 24 h Analysis Open analysis with  Menu  >  Diagnostics  >  Analysis . Analysis: Average values Characetristics You can now choose between viewing the  Average Values  and the  Characteristics . Esc. Meas Average Values Selecting  Average Values  will display – the most recent 1/2 h average value with deviation will be and (if enough measurement values are available) Average Values 0217.09.15 23:30:00 ZrOx 24h average values: insufficient values! 1/2h average value: 19.259 % +- 710 ppm – the 24 h average value with deviation Use the # and $ keys to select the channel. Esc. Meas Characteristics Selecting  Characteristics  will display a graph of the 1/2 h average values recorded. The last average value recorded will appear at the right edge of the graphic and will be slightly larger than the other measuring points. Characteristics O2ZrOx Use the  and ž keys to move the marker inside the graphic. The value below the time axis corresponds to the 1/2 h average value of the respective marked point. (The 3rd last measuring point is marked in the example.) 20.087 17.01.15 09:30:00 20.90% 20.265 % +- 284 ppm Meas t Esc. 7.3 Menu > Base Settings Use the base settings menu to configure the device settings. Menu Description Language Choose from German and English as the menu language. Passwords Add passwords 1 and 2 or enable / disable password protect Pressure sensor Here enter the current air pressure. This serves as a reference value for adjusting the measurement values. Date/Time Set the current date and time. Pumps Define the behaviour for the installed pumps. 32 Bühler Technologies GmbH BE550021 ◦ 01/2017 BA 3 select 7.3.1 Menu > Base Settings > Passwords All parameters are protected from unauthorised access with a 3 character password. The default passwords at the time of delivery are:  Password 1 111  Password 2 222 Depending on the parameter relevance these are protected by password 1 or 2. The passwords may be changed and you can disable / enable password protect. Passwords Press  Menu  >  Base Settings  >  Passwords Password Protect: Off On Password protect is enabled on delivery,  On  is selected. Password 1 Password 2 Esc. Meas Enable/disable password protect – To disable the passwords, press  Off  and press this setting. 8 to save Password Protect: 8 Off Info NOTICE! All parameters can now be accessed at all times! To enable the passwords, press  On  and press setting. On Password 1 saved ! Password 2 OK to save this Esc. Meas Change password – Select  Password 1  or  Password 2  to change. Enter new PW1 Password Protect: – Enter a new password (max. 3 characters). – Press 8 to confirm your input. Password 1 – Repeat the new password. – Press 8 to confirm your input. The information will be saved. 7 8 9 4 5 6 1 2 3 0 Meas C Password Protect: NOTICE! Make a note of the new passwords and keep them in a safe location. Esc. On Off Info Password 1 saved ! Password 2 OK Esc. Meas 7.3.2 Menu > Base Settings > Language Changing the menu Use  Menu  >  Base Settings  >  Language  to open the droplanguage down menu. Base Settings Language Passwords Pressure sensor Date/Time Pumps Meas Select the language and press 8 to confirm your input. Press  OK  to acknowledge the message "Data saved”. Esc. Language: German Meas BE550021 ◦ 01/2017 English Esc. Bühler Technologies GmbH 33 BA 3 select 7.3.3 Menu > Base Settings > Pressure Sensor The analyser can be equipped with pressure sensor for compensating the pressure in the results. This will compute the ideal gas compensation for measurement fluctuations due to barometric or process-related pressure fluctuations. The drift of the internal pressure measurement is low enough for virtually all measuring tasks that an additional recalibration of the pressure sensor is not necessary. For high-precision measurements within minimal measuring ranges it may be helpful to recalibrate the pressure sensor. This requires a very accurate pressure gauge (0.1 mbar resolution) to measure the current ambient pressure. To calibrate the internal pressure sensor: Preparation – Shut off the internal and external sample gas pumps and prevent pressure fluctuations in the sample gas line at the process or gas output end (if necessary, disconnect the unit from the sample gas lines) – Use your external pressure gauge to measure the current ambient pressure and wait for the measurement value to stabilise. Pressure sensor If the pressure output by the analyser significantly deviates from your measurement value, select  Menu  >  Base Setting  >  Pressure Sensor  and enter password 2. Base Settings Language Passwords Pressure sensor Date/Time Pumps Meas Now select  Input , enter the value and press your input. 8 to confirm – Round your measurement value up or down, enter the new value and press 8 to confirm your input. Press 8 to confirm again and apply the change. Use  Meas  to return to the measurement screen. Esc. Pressure Sensor: Signal: 1.027 V Press.: 1044 mbar Input 1045 mbar Esc. Meas 7.3.4 Menu > Base Settings > Date/Time To set the current date and (local) time: Setting the date / time Press  Menu  >  Base settings  >  Date/Time Date/Time: Now select  Date  or  Time . Date 16.01.15 Time 11:14:50 AM Esc. Meas Enter the current values using the on-screen keyboard. (The example uses  Time .) Date – Time format: hours:minutes:seconds Time – Date format: Day.Month.Year (2-digit) – Press 8 Bühler Technologies GmbH 7 8 4 5 6 1 2 3 9 : 0 to confirm your input. Meas 34 hh:mm:ss AM Date/Time C Esc. BE550021 ◦ 01/2017 BA 3 select 7.3.5 Menu > Base Settings > Pumps Use this menu to specify the pump behaviour (where applicable) for each channel. Pumps Press  Menu  >  Base Settings  >  Pumps . Pumps: Pump 1 On Cal Pump 2 On Cal Esc. Meas Select the pump for which you wish to change the settings. The selected entry will be displayed inverted. Now change the setting with the # and $ Pumps: Pump 1 Off Pump 2 On Cal keys.  Off The pump is always off.  On The pump is always on.  On Cal The pump is only on during calibration. Esc. Meas Now select the next pump and define its settings. Finally, press saved. 8 to confirm your input. The settings will be 7.4 Menu > Channel Settings The following settings can be configured for each channel: Menu Description Measuring ranges Define the measuring range and the switchover points. Limits Define the gas concentration limits which will trigger a signal at the relay output. Outputs Parametrise the outputs. Units Select the unit to display the result in. Damping Define the damping constant for the measurement. Adjustment This menu item is only relevant when using the paramagnetic O2 cell. Here you will define the adjustment for carrier gases which may be present. BE550021 ◦ 01/2017 Bühler Technologies GmbH 35 BA 3 select 7.4.1 Menu > Channel Settings > Meas. Range You can define measuring range MR1 and MR2 for each channel. The settings will affect the output via the analogue output. The measuring range the unit is in can optionally be indicated via relay outputs. Depending on the setting under  Auto Switchover  two scenarios should be distinguished: 1.  Auto Switchover  is  Off : – The unit will measure in the resolution for measuring range MR1, with arbitrary configuration. – The output range of the analogue output corresponds to the range limits of measuring range MR1. 2.  Auto Switchover  is  On  : – The unit will now automatically switch between MR1 and MR2 if the current measurement value runs over or under the range limits (switchover points). – The output range of the analogue output corresponds to the range limits of the respective active measuring range. – The measuring range is displayed based on the  Auto Switchover  settings. To define the measuring range: Measuring ranges Select  Menu  >  Channel Settings  >  Meas. Range . Meas. range: Manual Settings Auto Switchover Esc. Meas Select  Man. Setting . First use the  MR1 . # and Manual Settings: $ keys to select the channel, then Enter the lower measuring range end value using the on-screen keyboard. Press 8 to confirm your input. This value will be applied to both measuring ranges. 02-ZrOx MR1 0 - 25% MR2 0 - 100 % Esc. Meas Then enter the upper measuring range end value for MR1 and press 8 again to confirm your input. Now select MR2 . Press 8 to confirm the lower value, then enter the upper measuring range end value for MR2. Press 8 to apply the new parameters and  Esc  to return to the next higher menu. Meas. range: Manual Settings Auto Switchover Esc. Meas Auto measuring range switchover Now under  Auto Switchover  define whether to enable automatic measuring range switchover. – Selecting  On  will enable automatic switchover of the measuring range. The analogue output signal will automatically be adjusted to the respective measuring range end values when the measuring range is switched over. Auto Switchover: 02-ZrOx switch. MR1 -> MR2 90 % MR1 switch. MR2 -> MR1 75 % MR1 Meas On Esc. – When selecting  Off , the desired measuring range must then be manually adjusted under  Manual Settings . – If necessary, define the switchover points  MR1 -> MR 2  and  MR2 -> MR1 . – Press 36 Bühler Technologies GmbH 8 to accept the settings. BE550021 ◦ 01/2017 BA 3 select 7.4.2 Menu > Channel Settings > Limits You may define two limits per channel and choose whether to signal if the respective limit is overrun or underrun. The signal will be output via the RS232 port, the relay outputs at the back of the unit and with notifications in the unit's display. How these signals will be handled is the responsibility of the owner. Limits Press  Menu  >  Channel Settings  >  Limits  and select  Limit Value 1  or  Limit Value 2 . Grenzwerte: 02-ZrOx Limit Val.1 < 19,0 % Limit Val.2 > 21,0 % Meas First enter the relational operator  >  or  < , then the value. (If you only enter one value, the original operator will be used.) Press 8 to confirm your input. Esc. < 20.0 Limits: Limit Value 1 Limit Value 2 7 8 4 5 6 1 2 3 9 0 Meas Lastly, press 8 to apply the new parameters and press  OK  to confirm the message. > , < C Limits: Esc. 02-ZrOx Limit Info Value 1 < 20.0 % Data saved ! Limit Value 2 > 22.0 % OK Esc. Meas 7.4.3 Menu > Channel Settings > Outputs In this menu you can define how the analogue output behaves for each channel and the parameters for the RS232 port. Analogue output Press  Menu  >  Channel Settings  >  Outputs  and select  Analog Output . Outputs: RS-232 Analog Output Esc. Meas Output Select the channel. Analog Output: Tap to select  Output  and define which signal the measurement output for the channel should output. Output 02-ZrOx 4-20mA Value at Cal Hold Value Value at Alarm Hold Value Esc. Meas Use # and $ to browse the list and press the respective setting. Choose from 8 to confirm Analog Output: Output 02-ZrOx 4-20mA – 4-20 mA (factory setting) – 0-20 mA – 2-10 V – 0-10 V Value at Cal. Hold Value Value at Alarm Hold Value Meas Esc. The analogue output scaling varies according to the measuring range MR1 or MR2 settings. The lower value under MR1 is identical with that under MR2 and corresponds with the lower analogue value. The upper analogue value corresponds to the end value of BE550021 ◦ 01/2017 Bühler Technologies GmbH 37 BA 3 select the respective active measuring range. Please note, in automatic switchover the measuring ranges of the end value will automatically be adjusted. This must be considered when analysing the analogue signal. Cal. failure You can further define the behaviour of the analogue output on calibration and failures. The settings can be configured independently. Mark  Value at Cal.  or  Value at Alarm , browse through the list using # and $ , and press 8 to confirm the respective setting. Choose from Analog Output: 02-ZrOx Output 4-20mA Value at Cal. Hold Value Value at Alarm Hold Value Esc. Meas – Hold Value (factory setting) – Zero – Current value Note: With the setting for "Value at Alarm" taking priority over the setting "Value at Cal."; i.e.: If an error occurs during calibration, the measurement will be handled as configured in "Value at Alarm". 7.4.4 Menu > Channel Settings > Units If a ZrOx measuring cell is installed, you can choose whether to display the measurements in Vol.% or ppm for the respective channel. The unit cannot be changed for other measuring cells. Please note, when selecting “ppm”, the maximal measuring range setting is 10,000 ppm. However, the measured value display will register up to 210,000 ppm. Displaying the measurement values in the unit ppm is only useful when measuring traces of O2. Units Open  Menu  >  Channel Settings  >  Units . Select the channel using # and $ Units: . 02-ZrOx Display Vol. % Now select  Display . Esc. Meas Now select the unit with # and $ . Depending on the cell type you will be able to choose from various units. Units: 02-ZrOx Display ppm Esc. Meas Press 8 to apply the new parameter and press  OK  to confirm the message. Units: 02-ZrOx Info Display Meas 38 Bühler Technologies GmbH Data saved ! Vol. % OK Esc. BE550021 ◦ 01/2017 BA 3 select 7.4.5 Menu > Channel Settings > Damping This submenu item is used to set the time constant (integration time) for damping the measurement display (moving average value). It represents the amount of time over which the measurement values are averaged before being output to the display. The values are 1 s to 20 s. The time constant factory setting is 1 s. delta t Press  Menu  >  Channel Settings  >  Damping . Select  delta t  and set the time constant using the and $ buttons. Press 8 Damping: # 02-ZrOx 1 sec delta t to accept the setting. Esc. Meas 7.4.6 Menu > Channel Settings > Adjustment This menu item only pertains to O2measurements by paramagnetic cell. Here you can enter the values from the table Adjustments β for common carrier gases (values for other gases upon request) [> page 13]. NOTICE Adjustment prefix When entering the adjustment be sure to add the opposite sign from the table! Adjustment value Press  Menu  >  Channel Settings  >  Adjustment . Select  Influence Carr. Gas  and enter the adjustment (including opposite sign). Press 8 Carrier Gas Adj.: 02-Para Influence Carr. Gas 0.00 Vol.% to accept the setting. The value will be rounded to 2 decimals. Esc. Meas 7.5 Menu > Calibration The following settings can be configured under menu item Calibration: Menu Description  Auto Here you can define whether to regularly auto-calibrate the unit.  Manual This menu item allows you to start a calibration with defined concentrations of zero and span gas.  Period Used to define the purging time and calibration period for the calibrating gases.  Deviation Enter the maximum concentration deviation to maintain during calibration.  Logbook The logbook records both the calibrations performed and events during calibration. BE550021 ◦ 01/2017 Bühler Technologies GmbH 39 BA 3 select 7.5.1 General information The properties of measuring instruments change over time due to components ageing or due to changes in ambient or process conditions. The resulting change in the measurement values is referred to as drift. To be able to measure with adequate accurate the unit regularly needs to be calibrated. This particularly applies when measuring very low gas concentrations. There is no one fit all calibration frequency as it depends on various factors. Important factors could be: – Changes in the unit’s ambient conditions (e.g. pressure and temperature) – Changes in the gas input conditions (e.g. gas temperature, gas flow rate, gas pressure) – Changes to the gas conditioning system (e.g. filter replacement, replaced devices) – Changes in the unit’s installation site or the installation position – Changes in the composition of the sample gas (e.g. changes in the concentration of carrier gases, sample gas moisture) – Switching measuring ranges Regardless of the above factors, drift will occur due to the age of components or measuring cell wear. Whilst this drift is typically quite minimal, we recommend calibrating the unit at least every 2-4 weeks. The effect of pressure variations can be compensated with the optional pressure sensors installed in the unit. Calibration is only sensible once the unit has reached a stable operating temperature (approx. 30 min after switching on). We recommend generally repeating the calibration after 60 min. When measuring very low gas concentrations, allow the unit to warm up approx. 2 h before calibrating it. NOTICE Calibration results The best calibration results are achieved if the calibrating gas runs the exact same gas path as the sample gas, so flows to the unit through the entire gas conditioning system. Please also be sure the gas input and ambient conditions during calibration are the same as during measurement. 7.5.1.1 Calibrating gases In calibration we generally distinguish between zero gas calibration (1st reference point; zero point of the unit) and range calibration (calibrating a second reference point) for greater accuracy. This requires two different gases: Zero Gas When using EC cells and paramagnetic cells the zero gas should have a concentration of 20.9 Vol % (e.g. dry, clean ambient air without oil or grease) or 0 Vol. % (inert gases such as N2 or He). When using ZrOx measuring cells the oxygen concentration must be 20.9 Vol.%. Span gas A span gas concentration of 60-95 % of the measuring range value of the gas components to be measured is sensible. The best case scenario is a span gas concentration approximately the same as the expected sample gas concentration. 7.5.1.2 Special information about calibrating ZrOx measuring cells Although the analyser also supports two-point calibration of the ZrOx measuring cells, we generally recommend only one zero point calibration of the ZrOx cell using filtered ambient air or conditioned compressed air free from oil and water. This is for one due to the cell signal exponential depending on the oxygen concentration. Even minimal inaccuracies in the span gas greatly affect the signal sequence of the cell. Span calibration using gases with little mix accuracy can also result in great inaccuracies in the measurements. On the other hand this is a measuring principle with a precisely known course of the function. Sole zero point calibration with air will compensate all considerable cross-influences. Two-point calibration will only minimally improve the measurement accuracy at the lowest ppm measuring range (up to 200 ppm). Here the following is important: – The span gas used should be considerably more accurate than the desired measurement accuracy. – The span gas concentration should be as close to the expected application measurement as possible. 40 Bühler Technologies GmbH BE550021 ◦ 01/2017 BA 3 select 7.5.1.3 Calibration presets In addition to the settings for calibrating gas concentrations the Calibration Period, the Purging Time and the acceptable Deviation must be defined. Here these parameters are defined as follows: Cal.Period The required amount of time for which calibrating gas (zero or span gas) should flow through the analyser for good calibrating results. These should be assessed so the calibrating gas flows through the unit (without supply lines) for at least 1 min. The calibration period factory setting is 3 min. Purging time The amount of time for which the analyser is purged with calibrating gas prior to calibration to prevent calibrating gas and sample gas being mixed during calibration. These should be assessed so the calibrating gas flows through the unit (without supply lines) for at least 1 min. Please also remember the amount of time the calibrating gas requires from the sampling point to the analyser. Die purging time factory setting is 3 min. Deviation The maximum permissible deviation between the zero gas or span gas setpoint setting and the actual measurement values / displayed values during calibration (in % from setpoint). The factory setting for this parameter is 1 Vol.% O2 absolute for zero gas and 5 % (from the target value) for the span gas. Time period This corresponds to the time period after which automatic calibration should be repeated cyclically. It is only enabled when set to “Auto Calibration ON". 7.5.2 Menu > Calibration > Period Period Select  Menu  >  Calibration  >  Period . Enter password 2 and press 8 to confirm. You can now set the calibration period and purging time. Period: The factory setting is 3 min. First use the # and  All Channels . $ keys to select the channel or 02-ZrOx Cal.Period 3:00 min Purging Time 3:00 min Esc. Meas Cal.Period / Purging Select  Cal.Period  or  Purging Time . Time Enter the new time in the format minutes:seconds, e.g. 05 : 30  for 5 min, 30 sec. Cal.Period Purging Time Note: A two-digit input is interpreted as “seconds"; e.g. entering  99  8 will result in a period of 1:39 min. 8 to confirm your input. 7 8 9 4 5 6 1 2 3 : 0 Meas Press hh:mm:ss AM Purging Time: C Esc. When setting the period please allow for the length of the lines from the calibrating gas delivery point and the analyser. – The maximum calibration period or purging time setting is 10:00 minutes. BE550021 ◦ 01/2017 Bühler Technologies GmbH 41 BA 3 select 7.5.3 Menu > Calibration > Deviation Calibration Deviation Select  Menu  >  Calibration  >  Deviation . 8 Enter password 2 and press Calibration to confirm. Auto Manual Period Deviation Logbook Meas Now use $ and  All Channels . # to select the channel or Tolerance Cal. Var.: Use the # and $ keys to select the channel  Span Gas  to define the span gas concentration. Confirm each input with 8 Esc. 02-ZrOx Span Gas 10.0% fr. setpoint Zero Gas 1 % O2 absolute . Esc. Meas Span Gas Enter the new limit value as "% from setpoint" under  Span Gas . Input range: 0.5 % to 20 % from setpoint Press 8 10.0 Tolerance Cal. Var.: Span Gas to confirm your input. Zero Gas 7 8 4 5 6 1 2 3 9 , 0 Meas Zero Gas (Inert gas or 20,9 Vol% O2 allowed) Here, the calibration deviation is factory-set to 1 Vol% O2. This value cannot be changed C Tolerance Cal. Var.: Press  Esc  to return to the next higher menu. Esc. 02-ZrOx Span gas 5.0% fr. setpoint Zero Gas 1% O2 absolute Esc. Meas 7.5.4 Menu > Calibration > Auto Auto-calibration Select  Menu  >  Calibration  >  Auto . Enter password 2 and press 8 Calibration to confirm. Auto Manual Period Deviation Logbook Meas The zero gas concentration for the paramagnetic cell and the EC cell should be set to 0 Vol. % (e.g. nitrogen 5.0) or 20.9 Vol. % (dry, clean ambient air free from oil and grease). When using the ZrOx cell the setting must be 20.9 Vol. % (dry, clean ambient air free from oil and grease). Auto Calibration: Esc. 02-ZrOx Zero Gas 20,9 % Span Gas 0.1 % Time Period Off 10:00:00 h Esc. Meas Span Gas To define the span gas concentration, first select the channel using the keys # and $ . Zero Gas Then mark  Span Gas . Enter the desired concentration using the on-screen keyboard. Press 42 Bühler Technologies GmbH 8 to apply the value. 20,9 Auto. Calibration: Span Gas Time Period Meas 7 8 4 5 6 1 2 3 0 9 , C Esc. BE550021 ◦ 01/2017 BA 3 select Time Period Now select  Time Period . Enter the auto calibration interval in the format hours:minutes:seconds. Press 8 hh:mm:ss PM Auto. Calibration: Zero Gas Span Gas to confirm your input. 7 8 9 4 5 6 1 2 3 Time Period 0 Meas Auto. calibration: Off / On To enable/disable auto calibration, toggle the mode with the  Off  or  On  key. C Auto Calibration:  Off  - auto calibration is disabled. : 02-ZrOx Zero Gas 20,9 % Span Gas 0.1 % Time Period Esc. Off 10:00:00 h Esc. Meas  On  - after applying the settings with 8 the initial calibration will start and will then be repeated after the defined time period. Auto Calibration: Press  Esc.  to return to the next higher menu or  Meas  to return to the measurement screen. 02-ZrOx Zero Gas 20,9 % Span Gas 0.1 % Time Period On 10:00:00 h Esc. Meas The logbook records both the calibrations performed and events during calibration. 7.5.5 Menu > Calibration > Manual A manual calibration may be performed at any time. Manual Calibration Select  Menu  >  Channel Settings  >  Manual . Calibration Enter password 2. Now select All Channels  or use the arrow keys to navigate to the channel to be calibrated. # and $ Auto Manual Period Deviation Logbook Meas When selecting  Zero Gas , select the concentration for the zero gas and press 8 to continue. Manual Calibration: The zero gas concentration for the paramagnetic cell and the EC cell should be set to 0 Vol. % (e.g. nitrogen 5.0) or 20.9 Vol. % (dry, clean ambient air free from oil and grease). When using the ZrOx cell the setting must be 20.9 Vol. % (dry, clean ambient air free from oil and grease). Esc. 02-ZrOx Zero Gas 20.9% Start Span gas 0.1 % Start Esc. Meas First press  Start   for the zero gas. The analyser will begin the zero gas calibration. Purge zero gas – This process will take the amount of time specified under  Purging Time . The process may be stopped at any time with Esc. . After the purging time calibration with zero gas will automatically start. O2-ZrOx: 30% Zero Gas Purging 10,0% 5 sec BE550021 ◦ 01/2017 20 19,5% 0 0 Esc. Bühler Technologies GmbH 43 BA 3 select Calibrate zero gas This process will take the amount of time specified under  Cal.Period . The process may be stopped at any time with Esc. . O2-ZrOx: 20 20,1% 0 30% 0 Zero Gas Calibration 10,0% 8 sec Span Gas Now select  Span Gas , enter the concentration for the span gas and press 8 to confirm. Manual Calibration: Press  Start   to begin the calibration sequence for the span gas. Esc. 02-ZrOx Zero Gas 20.9% Start Span gas 0.1 % Start The process may be stopped at any time with Esc. . Esc. Meas The logbook records both the calibrations performed and events during calibration. 7.5.6 Menu > calibration > Logbook The logbook records all messages triggered during the calibration sequence. Successful calibrations are also recorded. View Logbook – Select the messages with  Menu  >  Calibration  >  Logbook . Calibration Enter password 2. Auto Manual Period Deviation Logbook Meas Plain text Esc. – Messages are displayed in plain text: Calibration log – Channel no, date and time 1. Ch. 1 -- 16.01.15 15:11:58 Cal. zero gas deviation failure – Plain text message. 2. Ch. 1 -- 16.01.15 15:12:51 Cal. zero gas deviation failure The process may be stopped at any time with Esc. . 3. Ch. 1 -- 16.01.15 15:13:31 Cal. span gas deviation failure Meas 1-3/3 Del 15:19:13 Esc. If an error message is triggered, proceed as follows: Verify – the unit had adequate time to warm up (at least 30 min) and stable operating conditions were reached. – Calibrating gases are loaded in the desired concentration, – the settings under Auto or Manual are correct and correspond with the respective gases. – the calibrating gas supply is working properly and the purging time and cal.period settings are adequate. Delete the respective top message (1st) with the Del button until all messages have been deleted. Restart calibration. If calibration fails again, you may be able to find information in chapter "" or contact our service (see chapter "Service and repair [> page 49])". 44 Bühler Technologies GmbH BE550021 ◦ 01/2017 BA 3 select 8 Service During maintenance, remember: – The equipment must be maintained by a professional familiar with the safety requirements and risks. – Only perform maintenance work described in these operating and installation instructions. – When performing maintenance of any type, observe the respective safety and operation regulations. DANGER Electric voltage Risk of electric shock a) Disconnect the unit from the mains when performing any maintenance. b) Secure the equipment from accidental restarting. c) The unit may only be maintained and opened by instructed, competent personnel. Diagnostics Please also refer to the “Failure” and “Service” logs for information on failure messages and service. Diagnostics Failure Log Status Service Log Analysis Meas Esc. 8.1 Service schedule The service schedule is only a guide for the required service intervals and work. The owner is responsible for defining the service intervals considering the application conditions. NOTICE Leaks when using corrosive gases When using corrosive gases, regularly visually inspect the gas paths for damage. The intervals are based on the gases used, their concentration and their corrosiveness. Please also note the information on parts in contact with media in chapter "". Further observe the official or company regulations for your application and the failure and service messages output by the unit. Service Service interval Visual inspection 1 – 2 days Inspect and if necessary replace filter element (if applicable). 1 week Calibrate At least monthly Check tightness of gas paths, check built-in gas pump To be defined by the owner, at least every 6 months BE550021 ◦ 01/2017 Bühler Technologies GmbH 45 BA 3 select 8.2 Leak test Interval approx. 6 months (recommended) Leak test procedure Sample gas conditioning Fig. 7: Leak test set-up 1. Close the sample gas outlet on the analyser (2) and the sample gas inlet of your gas conditioning system gas tight (e.g. using a shut-off cock (1) + (3)). 2. Connect a nitrogen pressure cylinder with fine control valve (4) between the shut-off cocks anywhere along the sample gas path. 3. Install a pressure gauge (5) in the sample gas path between the two shut-offs. Measuring range approx. 25 kPa = 250 mbar = 250 hPa. 4. Use the fine control valve to carefully set a nitrogen gas pressure of 20 kPa = 200 mbar = 200 hPa and seal the N2 gas supply gas-tight (e.g. using a shut-off cock (6)). The leak rate Q for your measuring system is determined from Q =(Δp × V) / Δt Where: Internal volume of your measuring system in litres Pressure loss measured in mbar Measuring time in seconds V Δp Δt To ensure high quality oxygen measurement we recommend a leak rate of < 5x10-5 mbar L/s With respect to permitted leak rates please note the standards or legal requirements for your application. WARNING Toxic gases Conveying toxic gases may require the analyser to be tighter. Please observe the applicable national regulations. Highly toxic gases must not be used in the unit! 46 Bühler Technologies GmbH BE550021 ◦ 01/2017 BA 3 select 8.3 Replace filter element Replacement filter elements: Item no. Description 411509910 Type FE-E2, 5 count Replace the filter element (white fibreglass cartridge) at the latest when noticeably discoloured. – In the case of new applications, check the filter element daily and – extend the inspection interval until you are able to determine the ideal service interval. NOTICE Filter replacement / filter discolouration Depending on the measuring application the filter will not become discoloured as the dust is colourless. In this case use suitable measures to check the filter. Changing the filter: 1. Before opening the filter, verify there are no toxic or hazardous gases or components in the sample gas filter. If necessary, purge the unit with air. 2. Switch off the built-in or external sample gas pump and stop the sample gas supply (close valve). 3. Unscrew the filter cover counter-clockwise. 4. Remove the filter cover. 5. Remove the filter cartridge and check the condition. 6. If necessary, install a new filter cartridge. Be sure it is seated correctly. 7. Clean the sealing surfaces and seals and replace, if necessary. 8. Reinstall the filter cover without damaging the filter element. 9. Screw on the filter cover, turning clockwise 8.4 Replacing the EC cell To determine whether the cell needs to be replaced it should be charged with dry, clean air (20.5 -20.9% O2). If the signal now becomes too weak due to the age of the cell, the maintenance message "Replace EC cell" will appear. CAUTION Corrosion hazard EC measuring cells contain an acid or alkaline solution as the electrolyte. These could leak if the cell housing is damaged and corrode unprotected skin or the eyes. a) Only screw in or unscrew the cell by hand, do not use tools. b) If necessary, protect yourself from leaking electrolyte. Wear safety gloves and goggles. To replace an EC cell in the unit: Removal 1. Open the service door in the front face. Unscrew the two screws on the door for this purpose. 2. First squeeze the release to disconnect the plug connection between the cell plug and the mating connector without the need for tools. Now disconnect the cell plug. 3. Carefully unscrew the cylindrical cell body from the holder by hand, turning counter-clockwise. Installation 1. Install a new seal on the new cell. 2. Screw in the cell hand tight, turning clockwise. 3. Push the cell plug into the mating plug. 4. Secure the service door to the front of the device using the designated screws. 5. Record the cell replacement in your service list. 6. Perform a nullification as described in the following section. BE550021 ◦ 01/2017 Bühler Technologies GmbH 47 BA 3 select Nullification Any time a cell is replaced the cell signal must be nullified. Proceed as follows: 1. In the Diagnostics menu select the subitem Status 2. Use the arrow keys to navigate to the EC cell. Here you will see the button ON at the top right in the display 3. Pressing this will open the special menu Nullification. This functionality is about the same as a calibration. 4. Therefore first add (similar to zero gas calibration) dry, clean, air free from oil and grease (20.9% O2). 5. If the measurement value is stable, use the Start button to start "zero gas" nullification. 6. Then perform the "span gas" nullification. 7. To do so, add the respective span gas. 8. If the measurement value is stable, use the Start button to start "span gas" nullification. 8.5 Cleaning Regularly clean the outside of the housing using a soft, damp cloth. Only use mild cleaners. 8.6 Replacing fuses The BA3 select has two fuses at the back of the unit, F1 and F2. 9 F1 F2 Fig. 8: BA 3 select, rear view, fuses F1 is the fuse for the internal 24 V DC supply. F2 is built into the power socket and fuses the mains supply. – Disconnect the mains plug before replacing the fuses. – Only replace defective fuses with the same type. Fuse ratings: F1: 250 mA, delayed action F2: 1 A, delayed action 48 Bühler Technologies GmbH BE550021 ◦ 01/2017 BA 3 select 9 Service and repair This chapter contains information on troubleshooting and correction should an error occur during operation. Repairs to the unit must be performed by Bühler authorised personnel. Please contact our Service Department with any questions: Tel.: +49-(0)2102-498955 or your agent If the equipment is not functioning properly after correcting any malfunctions and switching on the power, it must be inspected by the manufacturer. Please send the equipment inside suitable packaging to: Bühler Technologies GmbH - Reparatur/Service Harkortstraße 29 40880 Ratingen Germany Please also attached the completed and signed RMA decontamination statement to the packaging. We will otherwise be unable to process your repair order. You will find the form in the appendix of these instructions, or simply request it by e-mail: service@buehler-technologies.com. 9.1 Status messages and troubleshooting Service notifications and equipment failures are written to the respective logbooks. The event is also indicated by – flashing icons in the measurement screen, – a status message from the measuring channel (Plug ST1 – ST4 at the back of the unit) or – an equipment status message (Plug ST0 at the back of the unit) Status signals are triggered by the respective relay contact switching over, also see chapter "". The following tables provide information on how to handle these messages. Open the respective logbook, take the specified actions and delete the respective logbook entry. Once all messages have been deleted the status signal will reset. 9.1.1 Service Log messages Information related to the next service is saved to the service log. Open:  Menu  >  Diagnostics  >  Service Log Logbook message Sym- Possible cause bol Replacing the EC cells  W  The cell signal from the electrochemical measuring cell is too weak due to cell wear. The cell measuring accuracy specified in the technical documentation is no longer guaranteed. > 20000h operating hours  W  The unit has been operating for over – Equipment service by Bühler is recom20000 hours. The measuring accuracy mended. Contact Bühler Service specified in the technical documentation is no longer guaranteed. BE550021 ◦ 01/2017 Action – The worn measuring cell should be replaced with a new cell; contact Bühler Service or send the unit to Bühler Bühler Technologies GmbH 49 BA 3 select 9.1.2 Failure Log messages Errors which occur during operation are saved to the failure log Open:  Menu  >  Diagnostics  >  Failure Log Logbook message Sym- Possible cause bol low temp  !  The cell temperature was temporarily be- – Delete the log entry low the operating temperature – For recurring errors check the ambient and service conditions; if neces(Alarm was automatically reset) sary, contact Bühler Service  A  Defective temperature sensor or measur- – Take unit out of service, contact ing cell heater Bühler Service Baro pressure comp. out of tolerance  A  Action negative pressure in the gas path incorrect – Observe or adjust permissible gas pressure  A  Defective internal barometric pressure sensor – Take unit out of service, contact Bühler Service  A  Internal equipment temperature > 55°C (e.g. due to excessive ambient temp.) – Ensure the ambient temperature is below 50°C  A  Defective cell heater – Take unit out of service, contact (if "Heater failure" message also appears) Bühler Service  A  Alarm due to over/underrrunning the – Adjust limits to process conditions concentration values set by the customer  !  Alarm was automatically reset. Heater failure  A  Measuring cell heater defective – Take unit out of service, contact Bühler Service out of tolerance  A  Incorrect measuring cell signal drift or defective measuring cell – Take unit out of service, contact Bühler Service T-Sensor failure  A  Measuring cell temperature sensor defective – Take unit out of service, contact Bühler Service Low gas flow  A  The minimum gas flow through the – Check sample gas lines and unit for measuring cell is significantly underrun leaks due to – Check gas supply and pump function– leaks, ality. Gas temperature failure Limit value over/ underrun – defective gas supply, – Clean clogged filters, lines, etc. – defective sample gas pump, – Check any shut-off valves in the gas path – clogged gas paths (e.g. filter, lines, etc.) Baro pressure comp. failure 50 Bühler Technologies GmbH  A  Barometric pressure sensor defective – Take unit out of service, contact Bühler Service BE550021 ◦ 01/2017 BA 3 select 9.1.3 Calibration Log messages Errors which occur during calibration are saved to the calibration log. Open:  Menu  >  Calibration  >  Logbook Logbook message Sym- Possible cause bol Variation failure  A  Excessive variation during calibration. Action Maintain a stable calibrating gas concentration during calibration, e.g. by: – Stabilising the sample gas flow. – Avoiding pressure variations in the gas path. – Increase calibrating gas purging times Cal. span gas deviation failure  A  The deviation between the defined calib- – Increase purging times for calibration ration setpoint and the value measured – Check calibration gas concentration. is greater than the limit set by the cus– Set the gas flow and gas pressure to tomer; permissible values – Incorrect calibrating gas, – if necessary, increase permissible cal – Insufficient gas flow, pressure ratios deviation values under menu item changed “Calibration" – Permissible cal deviation set too low Cal. span gas deviation failure  A  See "Cal span gas deviation failure" Cal successful No error Cal failed Error; calibration was rejected as the dis- – Correct or have the equipment error play currently shows an equipment error corrected, if necessary contact Bühler and is listed in the failure log. Service  A  --- – Delete logbook entries BE550021 ◦ 01/2017 Bühler Technologies GmbH 51 BA 3 select 10 Disposal Dispose of parts so as not to endanger the health or environment. Follow the laws in the country of use for disposing of electronic components and devices during disposal. 52 Bühler Technologies GmbH BE550021 ◦ 01/2017 BA 3 select 11 Appendices 11.1 Spare parts Item no. Description 553 603 00 ZrOx measuring cell 551 000 000 46 Electrochemical measuring cell 553 604 01 Paramagnetic cell 914 800 021 1 3/2 Solenoid valve 553 600 3 Bypass regulator 4346067 PVDF bulkhead coupling 9008525 VA bulkhead coupling 553 611 01 Standard pump 912 403 011 5 Brushless pump 4067002 Flow meter 2-20 l/h 9146030235 Plug connector 16 pin 9110000051 Fuse 4A delayed action for main board 9110000002 Fuse 1A delayed action for power connector 9110000017 Fuse 250mA delayed action for back of housing BE550021 ◦ 01/2017 Bühler Technologies GmbH 53 BA 3 select 11.2 Service list Service list BA 3 select Serial number Location Date 54 Service performed Bühler Technologies GmbH Name Signature BE550021 ◦ 01/2017 BA 3 select 12 Attached documents – Declaration of Conformity KX550012 – RMA - Decontamination statement BE550021 ◦ 01/2017 Bühler Technologies GmbH 55 RMA - Dekontaminierungserklärung RMA - Decontamination Statement DE/EN Gültig ab / valid since: 2014/11/01 Revision / Revision 1 ersetzt Rev. / replaces Rev. 0 Um eine schnelle und reibungslose Bearbeitung Ihres Anliegens zu erreichen, füllen Sie bitte diesen Rücksendeschein aus. Eine genaue Fehlerbeschreibung ist für die Ursachenanalyse nötig und hilft bei der schnellen Bearbeitung des Vorgangs. Die Aussage „Defekt“ hilft bei der Fehlersuche leider nicht. Please complete this return form to ensure your claim is processed quickly and efficiently. An accurate description of the problem is necessary for cause analysis and will help processing the claim quickly. Unfortunately, stating “defective” will not help us troubleshoot the issue. Die RMA-Nummer bekommen Sie von Ihrem Ansprechpartner im Vertrieb oder Service. You may obtain the RMA number from your sales or service representative. Zu diesem Rücksendeschein gehört eine Dekontaminierungserklärung. Die gesetzlichen Vorschriften schreiben vor, dass Sie uns diese Dekontaminierungserklärung ausgefüllt und unterschrieben zurücksenden müssen. Bitte füllen Sie auch diese im Sinne der Gesundheit unserer Mitarbeiter vollständig aus. This return form includes a decontamination statement. The law requires you to submit this completed and signed decontamination statement to us. Please complete the entire form, also in the interest of our employees’ health. Bringen Sie den Rücksendeschein mit der Dekontaminierungserklärung bitte zusammen mit den Versandpapieren in einer Klarsichthülle außen an der Verpackung an. Ansonsten ist eine Bearbeitung Ihres Reparaturauftrages nicht möglich! Attach the return form including decontamination statement along with the shipping documentation to the outside of the package, inside a clear pouch. Otherwise we are unable to process your repair order! Angaben zum Absender: Sender information: Firma / Company Ansprechpartner / Contact person Anschrift / Address Abteilung / Department E-Mai / E-Mail: Tel. / Phone Fax / Fax: Artikelnummer / Item number Auftragsnummer / Order number Anzahl / Quantity Rücksendegrund / Return reason RMA-Nr. / RMA no. Reparatur / Repair Garantie / Warranty Zur Prüfung / For inspection Rückgabe / Return Vorgangsnummer des Kunden / Customer transaction number:: Fehlerbeschreibung / Description of the problem: Ort, Datum / Place, Date Seite Page 1/2 Unterschrift / Stempel / Signature / Stamp: Bühler Technologies GmbH D - 40880 Ratingen, Harkortstr. 29 Tel.: + 49 (0) 2102 / 4989-0 Fax: + 49 (0) 2102 / 4989-20 e-mail: service@buehler-technologies.com Internet: www.buehler-technologies.com RMA - Dekontaminierungserklärung RMA - Decontamination Statement DE/EN Gültig ab / valid since: 2014/11/01 Revision / Revision 1 ersetzt Rev. / replaces Rev. 0 Bitte füllen Sie diese Dekontaminierungserklärung für jedes einzelne Gerät aus. Gerät / Device RMA-Nr / RMA no: Serien-Nr. / Serial no. [ ] Please complete this decontamination statement for each individual item Ich bestätige hiermit, dass das oben spezifizierte Gerät ordnungsgemäß gereinigt und dekontaminiert wurde und keinerlei Gefahren im Umgang mit dem Produkt bestehen. I herewith declare that the device as specified above has been properly cleaned and decontaminated and that there are no risks present when dealing with the device. Ansonsten ist die mögliche Gefährdung genauer zu beschreiben: In other cases, please describe the hazards in detail: Aggregatzustand (bitte ankreuzen): Aggregate state (please check): Flüssig / Liquid Fest / Solid Folgende Warnhinweise sind zu beachten (bitte ankreuzen): Pulvrig / Powdery Please note the following warnings (please check): Explosiv Explosive Giftig / Tödlich Toxic / lethal Entzündliche Stoffe Flammable substances Komprimierte Gase Compressed gasses Gesundheitsgefährdend Hazardous to health Gesundheitsschädlich Harmful to health Bitte legen Sie ein aktuelles Datenblatt des Gefahrenstoffes bei! Ort, Datum / Place, Date: Seite Page 2/2 Gasförmig / Gaseous Brandfördernd Oxidizing Umweltgefährdend Harmful to the environment Please include an updated data sheet of the hazardous substance! Unterschrift / Stempel Signature / Stamp: Bühler Technologies GmbH D - 40880 Ratingen, Harkortstr. 29 Tel.: + 49 (0) 2102 / 4989-0 Fax: + 49 (0) 2102 / 4989-20 e-mail: service@buehler-technologies.com Internet: www.buehler-technologies.com